醋酸乙酯提取物富集印楝生物柴油对铜的缓蚀作用

IF 1.2 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Periodico Di Mineralogia Pub Date : 2022-04-02 DOI:10.37896/pd91.3/9144
S. Iyyappan, P. Kannan, K. V. Kumar, V. Nagarajan
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引用次数: 0

摘要

以印度楝生物柴油为研究对象,在生物柴油中添加了抗氧化剂黑胡椒乙酸乙酯提取物,作为铜金属表面的缓蚀剂。对不同酸值和温度下的腐蚀速率和缓蚀效率进行了评价和分析。值得注意的是,ASTM D130评估显示生物柴油的缓蚀效率为98.0%。抑制剂在金属表面的脉冲吸附得到了负自由能和吸附热值的证实。利用扫描电镜(SEM)表面形貌记录研究了铜在缓蚀研究中的表面变化,揭示了缓蚀剂的保护性质。发动机的性能评估结果与印楝生物柴油和传统柴油本身相当。在此基础上,开发出了一种新的环境无害的生物柴油铜腐蚀缓蚀剂,具有实际应用价值。因此,该富集生物柴油可作为一种替代燃料,不仅具有良好的燃料价值,而且具有良好的缓蚀性。
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Enriched Neem Biodiesel With Piper Nigrum Ethyl Acetate Extract For Corrosion Inhibition Of Copper
Neem biodiesel is enriched with antioxidant Piper nigrum ethyl acetate extract as a corrosion inhibitor for copper metal surface. The corrosion rate and corrosion inhibition efficiency at different acid values and temperature were evaluated and analysed. Notably, ASTM D130 evaluation reveals 98.0% corrosion inhibition efficiency in biodiesel. Impulsive adsorption of inhibitors on the metal surface was substantiated by negative free energy and heat of adsorption values. SEM surface morphological recordings were employed to study the surface changes of copper subjected for corrosion inhibition studies that revealed the protective nature of the inhibitor. Engine performance evaluations are found to be on par with the results of neem biodiesel alone and conventional diesel itself. Based on the above results, a new environmental-harmless corrosion inhibitor for copper corrosion in biodiesel is unearthed for practical purpose. Hence, this enriched biodiesel can be used as an alternative fuel that not only has good fuel value but also corrosion inhibition.
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来源期刊
Periodico Di Mineralogia
Periodico Di Mineralogia 地学-地球化学与地球物理
CiteScore
1.50
自引率
14.30%
发文量
0
审稿时长
>12 weeks
期刊介绍: Periodico di Mineralogia is an international peer-reviewed Open Access journal publishing Research Articles, Letters and Reviews in Mineralogy, Crystallography, Geochemistry, Ore Deposits, Petrology, Volcanology and applied topics on Environment, Archaeometry and Cultural Heritage. The journal aims at encouraging scientists to publish their experimental and theoretical results in as much detail as possible. Accordingly, there is no restriction on article length. Additional data may be hosted on the web sites as Supplementary Information. The journal does not have article submission and processing charges. Colour is free of charges both on line and printed and no Open Access fees are requested. Short publication time is assured. Periodico di Mineralogia is property of Sapienza Università di Roma and is published, both online and printed, three times a year.
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