{"title":"PhanePhos及其衍生物","authors":"L. A. Adrio, K. K. Hii","doi":"10.1002/047084289X.RN01475","DOIUrl":null,"url":null,"abstract":"(R)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [364732-88-7] C40H34P2 (MW 576.65) \n \nInChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 \n \nInChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N \n \n \n \n \n \nPhysical Data: white solid, mp 222–226 °C. [α]d = −34 ± 4° (c 1, CHCl3). \n \n \n \n \n \n(S)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [192463-40-4] \n \nInChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 \n \nInChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N \n \n \n \n \n \nPhysical Data: white solid, mp 222–226 °C. [α]22d = +34° (c 1, CHCl3) \n \n \n \n(used as a chiral diphosphine ligand in transition metal-catalyzed reactions and also as organocatalyst) \n \n \n \nSolubility: not reported. \n \n \n \nForm Supplied in: white solid. Commercially available. \n \n \n \nHandling, Storage, and Precautions: readily oxidized to the phosphine oxide in solution and should be handled under N2 or Ar. Solid samples can be handled in air. Avoid contact with strong oxidizing agents and halogens.","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"54 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2012-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"PhanePhos and Related Derivatives\",\"authors\":\"L. A. Adrio, K. K. Hii\",\"doi\":\"10.1002/047084289X.RN01475\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"(R)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [364732-88-7] C40H34P2 (MW 576.65) \\n \\nInChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 \\n \\nInChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N \\n \\n \\n \\n \\n \\nPhysical Data: white solid, mp 222–226 °C. [α]d = −34 ± 4° (c 1, CHCl3). \\n \\n \\n \\n \\n \\n(S)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [192463-40-4] \\n \\nInChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 \\n \\nInChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N \\n \\n \\n \\n \\n \\nPhysical Data: white solid, mp 222–226 °C. [α]22d = +34° (c 1, CHCl3) \\n \\n \\n \\n(used as a chiral diphosphine ligand in transition metal-catalyzed reactions and also as organocatalyst) \\n \\n \\n \\nSolubility: not reported. \\n \\n \\n \\nForm Supplied in: white solid. Commercially available. \\n \\n \\n \\nHandling, Storage, and Precautions: readily oxidized to the phosphine oxide in solution and should be handled under N2 or Ar. Solid samples can be handled in air. Avoid contact with strong oxidizing agents and halogens.\",\"PeriodicalId\":11669,\"journal\":{\"name\":\"Encyclopedia of Reagents for Organic Synthesis\",\"volume\":\"54 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-09-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Encyclopedia of Reagents for Organic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/047084289X.RN01475\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/047084289X.RN01475","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
(R)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [364732-88-7] C40H34P2 (MW 576.65)
InChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N
Physical Data: white solid, mp 222–226 °C. [α]d = −34 ± 4° (c 1, CHCl3).
(S)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane [192463-40-4]
InChI = 1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChIKey = GYZZZILPVUYAFJ-UHFFFAOYSA-N
Physical Data: white solid, mp 222–226 °C. [α]22d = +34° (c 1, CHCl3)
(used as a chiral diphosphine ligand in transition metal-catalyzed reactions and also as organocatalyst)
Solubility: not reported.
Form Supplied in: white solid. Commercially available.
Handling, Storage, and Precautions: readily oxidized to the phosphine oxide in solution and should be handled under N2 or Ar. Solid samples can be handled in air. Avoid contact with strong oxidizing agents and halogens.
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