对硝基苯酚供体体系中质子转移和氢键的光谱研究

A.S.N. Murthy, A. Ram Reddy
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引用次数: 6

摘要

用电子吸收光谱法研究了对硝基苯酚在非质子溶剂和质子溶剂中与几种电子给体的相互作用。得到了1,2-二氯乙烷、正丁醇和乙腈中不同平衡态的平衡数据,并进行了讨论。用电子吸收光谱法研究了对硝基苯酚与多种电子给体在庚烷中的强氢键相互作用。从Mulliken的电荷转移模型中得到的有趣的相关性在许多情况下得到了检验和扩展。
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Spectroscopic studies on proton transfer and hydrogen bonding in p-nitrophenol-donor systems

The interaction of p-nitrophenol with several electron-donors has been studied in aprotic and protic solvents by electronic absorption spectroscopy. The equilibrium data for different kinds of equilibria in 1,2-dichloroethane, n-butanol and acetonitrile have been obtained and discussed. The strong hydrogen bonding interaction between p-nitrophenol and a variety of electron donors has been investigated in heptane by electronic absorption spectroscopy. The interesting correlations obtained in terms of Mulliken's charge transfer model have been examined and extended in many cases.

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