除铝后生物质焚烧鸟粪石- k沉淀的回收

E. Hidayat, Hadi Imran A. Halem, Y. Mitoma, H. Harada
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引用次数: 1

摘要

磷(P)和钾(K)是不可再生材料,广泛应用于许多工业,如农业部门。另一方面,随着全球人口的增加,作为肥料的磷和钾的需求也在增加。磷和钾的营养源分别来自生物质废弃物,即焚烧后的活性污泥和咖啡壳生物炭。本研究以鸟粪石-K (KMgPO4·6H2O)沉淀的形式回收P和K。结果表明:在Al:P为1:1,K:P为0.5,Mg:P为3的条件下,焚烧活性污泥中铝与磷同时释放;然而,铝被抑制形成鸟粪石- k。然后,我们研究了溶解0.5 M HNO3,并分别以KH2PO4和MgCl2·6H2O为K和Mg源的溶液对阳离子的去除,特别是对去除Al的去除。结果表明,铝(Al)的去除率为沉淀K:P为0.5,Mg:P为0.8。本研究证实焚烧后的生物质可成功回收为鸟粪钾,可作为肥料使用。
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Recovery of Biomass Incinerated as Struvite-K Precipitates Followed Aluminium Removal
Phosphorus (P) and potassium (K) are non-renewable materials and widely in many industries such as agricultural sectors. On the other hand, the demand of P and K as fertilizers increases which following global population. The nutrient source of P and K which get from biomass waste i.e. incinerated of activated sludge and coffee husk biochar, respectively. The present study was conducted recovery of P and K as struvite-K (KMgPO4·6H2O) precipitates. The results showed that aluminium was released simultaneously with P from incinerated activated sludge with precipitate of Al:P of 1:1, K:P of 0.5, and Mg:P of 3. However, aluminium was inhibited to form struvite-K. Then, we examined cation removal especially for removed Al by dissolved 0.5 M HNO3 and the solution was mixed with KH2PO4 and MgCl2·6H2O as source of K and Mg, respectively. The results showed aluminium (Al) was removed with precipitate K:P of 0.5, and Mg:P of 0.8. This study was confirmed that recovery of biomass incinerated was successful as struvite-K and can be used as fertilizers.
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