添加锶对生物可降解植入材料Mg-Zn-Ca合金力学和腐蚀性能的影响

Bowen Kong, D. Cho, Pil-Hwan Yun, Jeong-Hun Lee, Jin-young Park, I. Park
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引用次数: 1

摘要

添加Sr对铸态Mg-3wt.%Zn-0.5wt.%Ca-xwt. %力学和生物腐蚀性能的影响。研究了%Sr (x = 0.3, 0.6, 0.9)合金作为生物可降解植入材料的应用。采用光学显微镜、扫描电镜、拉伸试验和电化学测试等方法对铸态Mg-Zn-Ca-Sr合金的显微组织、力学性能和耐蚀性进行了表征。铸态合金中含有-Mg和共晶相,当Sr添加量大于0.3 wt.%时,合金中含有-Mg和Mg-Zn-Ca-Sr金属间化合物。随着Sr含量的增加,合金的屈服强度、极限抗拉强度和伸长率均有所提高,Sr含量为0.6 wt.%时合金的屈服强度、极限抗拉强度和伸长率有所降低,而Sr含量为0.3 wt.%时合金的耐腐蚀性优于其他合金。过量的Mg-Zn-Ca-Sr金属间化合物使铸态合金的力学性能和耐腐蚀性恶化。
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Effect of Sr Addition on Mechanical and Corrosion Properties of Mg-Zn-Ca Alloy for Biodegradable Implant Material
The effect of Sr addition on mechanical and bio-corrosion properties of as-cast Mg-3wt.%Zn-0.5wt.%Ca-xwt.%Sr (x = 0.3, 0.6, 0.9) alloys were examined for application as biodegradable implant material. The microstructure, mechanical properties and corrosion resistance of the as-cast Mg-Zn-Ca-Sr alloys were characterized by using optical microscopy, scanning electron microscopy, tensile testing and electrochemical measurement in Hank's solution. The as-cast alloys contained -Mg and eutectic phases, while the alloys contained -Mg, and Mg-Zn-Ca-Sr intermetallic compound when the Sr addition was more than 0.3 wt.%. The yield strength, ultimate tensile strength and elongation increased with the increasing of Sr content up to 0.6 wt.% but decreased in the 0.9 wt.% Sr-added alloy, whereas the corrosion resistance of 0.3 wt.% Sr-added alloy was superior to other alloys. It was thought that profuse Mg-Zn-Ca-Sr intermetallic compound deteriorated both the mechanical properties and corrosion resistance of the as-cast alloy.
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