不饱和脂肪酸衍生物中乙基乙酯的加成

Fett-lipid Pub Date : 1999-06-01 DOI:10.1002/(SICI)1521-4133(199906)101:6<199::AID-LIPI199>3.0.CO;2-4

A. Behr, M. Fiene

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引用次数: 6

摘要

不饱和脂肪酸衍生物加成乙基乙酯的收率最高可达89%。产物是相应的1:1加合物。对反应温度、反应时间、化学计量和脂肪酸衍生物的浓度进行了研究和优化。当油酸乙酯用量增加4倍，反应温度为200℃，反应时间为24 h，油酸乙酯浓度为1.3 mol/l时，收率最高。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives

The addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives occurs with a maximum yield of 89%. The products are the corresponding 1:1-adducts. Temperature, reaction time, stoichiometry, and the concentration of the fatty acid derivative were investigated and optimized. A maximum yield was obtained with a fourfold excess of oleic acid ethyl ester, a reaction temperature of 200°C, a reaction time of 24 h, and an oleic acid ethyl ester concentration of 1.3 mol/l.

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Fett-lipid

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