{"title":"重氮乙酸酯与烯烃、炔烃、杂环和芳香族化合物的反应","authors":"V. Dave, E. Warnhoff","doi":"10.1002/0471264180.OR018.03","DOIUrl":null,"url":null,"abstract":"After the first unsuccessful attempt of Curtius in 1884 to affect the reaction of ethyl diazoacetate with toluene other researchers studied the reaction. Later, Buchner and Curtius treated several aromatic, olefinic, and acetylenic compounds with diazoacetic esters to form cyclopropanes. Since then the reactions of diazoacetates with various unsaturated compounds have been studied. The carbalkoxy carbenes are of interest since they are believed to be intermediates in higher temperature thermal and photochemical reactions of diazoacetates. \n \n \nKeywords: \n \ndiazoacetic esters; \nalkenes; \nalkynes; \nhetercyclic compounds; \naromatic compounds; \nbenzene; \nderivatives; \nstereochemistry; \npolynuclear aromatics; \nexperimental conditions; \npreparation","PeriodicalId":19539,"journal":{"name":"Organic Reactions","volume":"2 1","pages":"217-401"},"PeriodicalIF":0.0000,"publicationDate":"2011-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"The Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocyclic and Aromatic Compounds\",\"authors\":\"V. Dave, E. Warnhoff\",\"doi\":\"10.1002/0471264180.OR018.03\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"After the first unsuccessful attempt of Curtius in 1884 to affect the reaction of ethyl diazoacetate with toluene other researchers studied the reaction. Later, Buchner and Curtius treated several aromatic, olefinic, and acetylenic compounds with diazoacetic esters to form cyclopropanes. Since then the reactions of diazoacetates with various unsaturated compounds have been studied. The carbalkoxy carbenes are of interest since they are believed to be intermediates in higher temperature thermal and photochemical reactions of diazoacetates. \\n \\n \\nKeywords: \\n \\ndiazoacetic esters; \\nalkenes; \\nalkynes; \\nhetercyclic compounds; \\naromatic compounds; \\nbenzene; \\nderivatives; \\nstereochemistry; \\npolynuclear aromatics; \\nexperimental conditions; \\npreparation\",\"PeriodicalId\":19539,\"journal\":{\"name\":\"Organic Reactions\",\"volume\":\"2 1\",\"pages\":\"217-401\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Reactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/0471264180.OR018.03\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Reactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/0471264180.OR018.03","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocyclic and Aromatic Compounds
After the first unsuccessful attempt of Curtius in 1884 to affect the reaction of ethyl diazoacetate with toluene other researchers studied the reaction. Later, Buchner and Curtius treated several aromatic, olefinic, and acetylenic compounds with diazoacetic esters to form cyclopropanes. Since then the reactions of diazoacetates with various unsaturated compounds have been studied. The carbalkoxy carbenes are of interest since they are believed to be intermediates in higher temperature thermal and photochemical reactions of diazoacetates.
Keywords:
diazoacetic esters;
alkenes;
alkynes;
hetercyclic compounds;
aromatic compounds;
benzene;
derivatives;
stereochemistry;
polynuclear aromatics;
experimental conditions;
preparation
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
