乙二醇低聚物在25℃水溶液中的相互扩散

L. Paduano, R. Sartorio, G. D’Errico, V. Vitagliano
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引用次数: 30

摘要

在整个摩尔分数范围内,测量了水溶液中某些乙二醇低聚物二元体系在25℃时的相互扩散系数。结果与活度和扩散内数据相结合,计算速度相互关系系数(VCCs)。有人试图从分子相互作用的角度来解释这些结果。
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Mutual diffusion in aqueous solution of ethylene glycol oligomers at 25 °C
Mutual diffusion coefficients have been measured, at 25 °C, for binary systems of some ethylene glycol oligomers in aqueous solution over the whole mole fraction range. The results have been combined with activity and intradiffusion data to calculate the velocity cross-correlation coefficients (VCCs). An attempt has been made to explain the results in terms of molecular interactions.
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