Cr2O3/ a - al2o3涂层对incoly 800H合金高温非纯氦腐蚀行为的影响

IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Journal of Nuclear Fuel Cycle and Waste Technology Pub Date : 2022-08-08 DOI:10.1115/icone29-90536
Haoxiang Li, Weizhen Zheng, B. Du, Huaqiang Yin, Zhihao Hong, Long Wang, Xuedong He, Tengyu Ma, Xingtuan Yang
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引用次数: 0

摘要

在高温气冷堆(HTGR)中,一次冷却剂中含有少量氦气(ppm级)不纯杂质,这些杂质会腐蚀高温堆的合金材料,影响设备在高温环境下的性能。合金表面的涂层制备技术可以有效地保护合金基体,大大降低合金的腐蚀速率,提高设备的可靠性和安全性。本文采用射频磁控溅射法制备Cr2O3/α-Al2O3多层阻挡层,对incoly 800H合金进行了涂层处理,研究了涂层前后incoly 800H合金在高温非纯氦条件下的腐蚀行为。实验结束后,通过称重、扫描电镜(SEM)和x射线能谱(EDS)对腐蚀结果进行分析。结果表明:Cr2O3/ α-Al2O3阻挡层在高温腐蚀后部分脱落;合金内部氧化现象不明显,涂层能抑制合金的氧化渗碳;腐蚀后合金的质量增加,涂层合金的质量增益低于未涂层合金。
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Effect of a Cr2O3/A-Al2O3 Coating on the Corrosion Behavior of Incoloy 800H Alloy in High Temperature Impure Helium
In high temperature gas cooled reactor (HTGR), there is a small amount of helium in the primary coolant (ppm level) impure impurities, which will corrode the alloy materials of high temperature reactor and affect the performance of equipment in high temperature environment. The coating preparation technology on the alloy surface can effectively protect the alloy matrix, greatly reduce the corrosion rate of alloy, and improve the reliability and safety of equipment. In this paper, a Cr2O3/α-Al2O3 multilayer barrier coating prepared by RF magnetron sputtering was used to coat Incoloy 800H alloy, and the corrosion behavior of Incoloy 800H alloy with and without coating under selected high-temperature impure helium was investigated. After the experiment, the corrosion results were analyzed by weighing, scanning electron microscope (SEM) and X-ray energy dispersive spectroscopy (EDS). The results showed that Cr2O3/ α-Al2O3 barrier coating partially fell off after high temperature corrosion; The internal oxidation phenomenon of the alloy was not obvious, and the coating can inhibit the oxidation and carburization of the alloy; The mass of the alloy increased after corrosion, and the mass gain of the coated alloy was lower than that of the uncoated alloy.
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来源期刊
CiteScore
0.80
自引率
25.00%
发文量
35
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