超声波辅助鲶鱼脂肪生产生物柴油

Intan Shafinaz Abd Manaf, Mohd Hasbi Ab. Rahim, Gaanty Pragas Maniam
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摘要

本文报道了超声辅助非均相固体催化(CaO)合成鲶鱼脂肪生物柴油的研究。超声波提供了一个更快的化学反应和速度的提高,参考的空化,导致压力和温度的积累,以及增加催化表面积和改善传质。与传统方法相比,该方法具有反应时间短、能耗低、甲醇与甘油三酯的摩尔比高、为混合提供机械能等显著优点。启动酯交换反应所需的活化能,因此,将油脂酯交换成生物柴油的产率更高。优化后的反应条件为:甲醇与油的摩尔比为15:1;催化剂(B-CaO), 9 wt. %;反应温度65±2℃;反应时间为1 h,工作频率为42 kHz,电源为100W。最高转化率达到96.4 wt. %。
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Biodiesel production from catfish (Pangasius) fat via ultrasound- assisted method
This paper reports studies in ultrasound-assisted heterogeneous solid catalyzed (CaO) synthesis of biodiesel from catfish (Pangasius) fat. Ultrasonication provides a faster chemical reaction, and the rate enhancements, refereed by cavitation that causes the building- up of pressures and temperatures, as well as increased catalytic surface areas and improve mass transfer. This novel method offers significant advantages such as shorter reaction time and less energy consumption than the conventional method, efficient molar ratio of methanol to triglycerides and provides the mechanical energy for mixing. The required activation energy for initiating the transesterification reaction and so, it gives a higher yield by transesterification of oils into biodiesel. The optimized reaction conditions were as follows: methanol to oil molar ratio of 15:1; catalyst (B-CaO), 9 wt. %; reaction temperature, 65 ± 2 °C; reaction time, 1 h at a working frequency of 42 kHz and the power supply of 100W. Highest conversion of 96.4 wt. % was achieved.
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