多层石墨烯对硬质合金极板电阻的影响

S. Eremin, V. N. Anikin, D. Rudenko, A. M. Kolesnikova, Y. Sobolev, V. Kuzin, M. Fedorov, N. A. Revyakina
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摘要

在本研究中,对vk10kom和VRK15级粉末进行了电化学涂覆多层石墨烯制备硬质合金的实验研究。在vk10kom和VRK15牌号的标准条件下烧结了含有多石墨烯的样品。在重量比中,vk10khm级合金的多石墨烯含量为0.1 wt. %, VRK15级合金的多石墨烯含量为0.1 wt. %和0.5 wt. %。VK10KhOM样品的摩擦试验表明,复合石墨烯样品的磨损区宽度比原始样品小8%。当石墨烯质量分数为0.1 wt. %时,vk10kom等级的密度为14.5,VRK15为14.0,孔隙率分别为0.02%和2%。对切削钛级VT-3进行了对比试验。通过切削,发现复合石墨烯粉末涂层增加了两种牌号硬质合金刀片的阻力。结果表明,对于VRK15级,板的耐久性提高了4倍,而对于vk10khm级,无法确定板的破坏时间。耐磨性的提高可能是由于多石墨烯溶解在硬质合金中,以纳米石墨团簇的形式析出,从而降低了摩擦系数。
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Effect of multigraphene on the resistance of plates from hard alloys
In the work, experiments were carried out on the production and testing of hard alloys from powders of the VK10KHOM and VRK15 grades coated with multigraphene obtained by the electrochemical method. Samples with multigraphene were sintered under standard conditions for grades VK10KHOM and VRK15. In the weight ratio, the amount of multigraphene was 0.1 wt. % for the VK10KHOM grade alloy and 0.1 wt. % and 0.5 wt. % for the VRK15 grade. Friction tests of VK10KhOM samples showed that the width of the wear areas of samples with multigraphene is 8 % less than in the original ones. At 0.1 wt. % graphene, the density of the VK10KHOM grade is 14.5 and VRK15 is 14.0, and the porosity is 0.02 % and 2 %, respectively. Comparative tests were carried out on cutting titanium grade VT-3. As a result of cutting, it was found that the coating of powders with multigraphene increases the resistance of carbide inserts of both grades. It is shown that for VRK15 the plate durability increased by 4 times, and for the VK10KHOM grade it was not possible to establish the plate failure time. The increase in wear resistance is presumably caused by a decrease in the coefficient of friction due to multigraphene, which, dissolving in the hard alloy, precipitates in the form of nanographite clusters.
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