技术说明:用于宇宙氖同位素分析的科隆Helix MC Plus多收集器惰性气体质谱仪的惰性气体萃取程序和性能

IF 2.7 Q2 GEOCHEMISTRY & GEOPHYSICS Geochronology Pub Date : 2021-08-19 DOI:10.5194/GCHRON-3-421-2021
B. Ritter, A. Vogt, T. Dunai
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引用次数: 10

摘要

摘要我们在科隆大学(德国)建立了一个新的惰性气体质谱实验室,专门用于宇宙核素的开发和应用。实验室的核心是最先进的高质量分辨率多收集器Helix MCPlus (thermofisher)惰性气体质谱仪和新型定制设计的自动萃取线。质谱仪配备了五个组合法拉第倍增器收集器,法拉第收集器配有1012 Ω和1013 Ω前置放大器。介绍了宇宙生成氖的提取线和自动化操作流程,以及实验装置的现状。使用大气同位素组成的气体(我们的主要标准气体)进行性能测试;以及CREU-1对比材料,其中含有大气和宇宙成分的氖的混合物。我们使用对CREU-1重复分析的结果来评估科隆目前实验装置的性能。测定宇宙成因21Ne丰度的精度等于或优于其他实验室的报告。我们得到的CREU中宇宙源性21Ne浓度的绝对值与已发表的值难以区分。
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Technical Note: Noble gas extraction procedure and performance of the Cologne Helix MC Plus multi-collector noble gas mass spectrometer for cosmogenic neon isotope analysis
Abstract. We established a new laboratory for noble gas mass spectrometry that is dedicated for the development and application to cosmogenic nuclides at the University of Cologne (Germany). At the core of the laboratory are a state-of-the-art high mass resolution multicollector Helix MCPlus (Thermo-Fisher) noble gas mass spectrometer and a novel custom-designed automated extraction line. The Mass-spectrometer is equipped with five combined Faraday Multiplier collectors, with 1012 Ω and 1013 Ω pre-amplifiers for faraday collectors. We describe the extraction line and the automized operation procedure for cosmogenic neon and the current performance of the experimental setup. Performance tests were conducted using gas of atmospheric isotopic composition (our primary standard gas); as well as CREU-1 intercomparison material, containing a mixture of neon of atmospheric and cosmogenic composition. We use the results from repeated analysis of CREU-1 to assess the performance of the current experimental setup at Cologne. The precision in determining the abundance of cosmogenic 21Ne is equal or better than those reported for other laboratories. The absolute value we obtain for the concentration of cosmogenic 21Ne in CREU is indistinguishable from the published value.
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来源期刊
Geochronology
Geochronology Earth and Planetary Sciences-Paleontology
CiteScore
6.60
自引率
0.00%
发文量
35
审稿时长
19 weeks
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