苯和苯衍生物中的暂时负离子共振

R.N. Compton , L.G. Christophorou, R.H. Huebner
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引用次数: 41

摘要

在苯及其六种衍生物的电子冲击激发谱中,发现了新的、强烈的、低于第一激发电位的能量损失共振。观察到的o-C6H4CH3Cl、C6H5Cl、C6H5Br和o-6H4Cl2的共振峰值与之前报道的这些化合物的解离电子捕获共振的能量完全相同,这表明这两种共振都是通过母体分子共同的暂时负离子状态进行的。
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Temporary negative ion resonances in benzene and benzene derivatives

New, intense, energy loss resonances below the first excitation potential were discovered in the electron impact excitation spectra of benzene and six of its derivatives. The observed resonances for o-C6H4CH3Cl, C6H5Cl, C6H5Br and o-6H4Cl2 peak at exactly the same energy as the dissociative electron capture resonances previously reported for these compounds, suggesting that both resonances proceed via a common temporary negative ion state of the parent molecules.

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