含磨粒高炉渣陶瓷废骨料砂浆氯离子扩散的时间依赖性

H. Higashiyama, M. Sappakittipakorn, M. Mizukoshi, O. Takahashi
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引用次数: 2

摘要

从我们之前的研究结果来看,在砂浆中回收陶瓷废骨料(CWA)已被证明是一种生态手段,而且对氯化物的进入有很好的效果。cwa是某电力公司提供的电瓷绝缘子废料,经粉碎磨成细骨料。在本研究中,为了进一步发展生态高效的水煤浆砂浆,加入了磨碎的粒状高炉渣(GGBS)。GGBS被用作补充胶凝材料(SCM),在水泥重量占比分别为15%、30%和45%三种不同的替代水平。采用电子探针微量分析(EPMA)方法,对GGBS增强水泥砂浆抗氯性的时间依赖性进行了实验研究。砂浆试样分别在5.0% NaCl溶液中浸泡24、48和96周。另一组砂浆样品在实验室环境条件下暴露24、48和96周,然后进行碳化测试。与GGBS的置换水平成正比,CWA砂浆的抗氯离子侵入性变得更有效。同时,随着GGBS的增加,CWA砂浆的碳化深度增加。明显的氯离子扩散系数之间的关系和矿渣微粉替代水平随着浸泡时间。
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Time Dependency on Chloride Diffusion of Ceramic Waste Aggregate Mortars Containing Ground Granulated Blast-Furnace Slag
From our previous findings, the recycling of ceramic waste aggregate (CWA) in mortar has been proved an ecological means plus an excellent outcome against chloride ingress. The CWAs were electric porcelain insulator wastes supplied from an electric power company, which were crushed and ground to fine aggregate sizes. In this study, to further develop the CWA mortar as an eco-efficient, ground granulated blast-furnace slag (GGBS) was incorporated. The GGBS was utilized as a supplementary cementitious material (SCM) at three different replacement levels of 15, 30, and 45% by weight of cement. The time dependency of the GGBS on enhancing chloride resistance in the CWA mortars was experimentally assessed by using an electron probe microanalysis (EPMA). The tests were carried out on mortar samples after immersion in 5.0% NaCl solution for 24, 48, and 96 weeks. Another set of the mortar samples was exposed to a laboratory ambient condition for 24, 48, and 96 weeks and then followed with a carbonation test. The resistance to the chloride ingress of the CWA mortar becomes more effective in proportion to the replacement level of the GGBS. Meanwhile, the carbonation depth of the CWA mortar increases with increasing the GGBS. The relationship between the apparent chloride diffusion coefficient and the GGBS replacement level was shown along with the immersion time.
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