黄斑天牛雌性接触性信息素21-甲基-8-五三康内烯四种可能立体异构体的合成

Eiichiro Fukusaki , Shiro Satoda , Hiroyuki Yuasa , Shuji Senda , Tetsuo Omata , Midori Fukaya , Sadao Wakamura
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引用次数: 6

摘要

从3-羟基-2-甲基丙酸、1-壬炔和1,10-癸二醇的对映体入手,合成了21-甲基-8-五三康内烯的4种可能的立体异构体,即(Z)-和(E)-几何异构体的(R)-和(S)-对映体,以评价雄性黄斑天牛Psacothea hilaris的反应。
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Synthesis of the four possible stereoisomers of 21-methyl-8-pentatriacontene, the female contact sex pheromone of the yellow-spotted longicorn beetle, Psacothea hilaris

The synthesis of the four possible stereoisomers of 21-methyl-8-pentatriacontene, the (R)- and (S)-enantiomers of both (Z)- and (E)-geometrical isomers, was achieved by starting from the enantiomers of 3-hydroxy-2-methylpropionate, 1-nonyne and 1,10-decandiol to evaluate the response of the male yellow-spotted longicorn beetle, Psacothea hilaris.

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