液体环己烷中振动弛豫时间的温度依赖性

A. Asenbaum
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引用次数: 0

摘要

用布里渊散射法测量了液体环己烷中超声声速和超声阻尼以及高超声速和弛豫时间τv1与温度的关系。这些数据表明了振动松弛比热的两步松弛过程。结果表明,在低温条件下,除两种最低振动模式外,其余所有振动模式都对第一松弛步骤的比热有贡献;在高温条件下,除三种最低振动模式外,其余所有振动模式都对第一松弛步骤的比热有贡献。根据布里渊线宽度得到的体粘度计算第二步的松弛时间τv2。对于体积黏度的非弛豫分数,利用相应态定理分别计算了氩和氪的对应值。最后,在硬球模型和单元模型的基础上,对最低振动模态失活所需的碰撞数Z10进行了计算。根据slavsky - herzfeld理论,在两个模型中都发现了In Z10与T−1/3之间的线性关系。
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Temperature dependence of the vibrational relaxation time in liquid cyclohexane

The temperature dependence of the ultrasonic velocity and ultransonic damping as well as the hypersonic velocity and relaxation time τv1 was measured in liquid cyclohexane by Brillouin scattering. These data suggest a two-step relaxation process for the vibrational relaxing specific heat. According to the results at low temperature all but the two lowest vibrational modes, at high temperature all but the three lowest vibrational modes, are contributing to the specific heat of the first relaxation step. The relaxation time τv2 of the second step was calculated based on the bulk viscosity derived from the Brillouin line width. For the non-relaxing fraction of the bulk viscosity the corresponding values of Argon and Krypton using the theorem of the corresponding states were applied.

Finally the collision number Z10 necessary for the deactivation of the lowest vibrational mode was evaluated on the basis of both the hard sphere model and the cell model. According to the Slawsky-Herzfeld theory a linear relationship between In Z10 and T−1/3 was found for both models.

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