Sc、Sr元素对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe铸造合金共晶mg2si变质及铸造性能的影响

Heon-Joo Kim
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摘要

研究了Sc和Sr元素对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe合金共晶相变质和浇注性能的影响。通过对冷却曲线的测量和微观组织的观察,分析了Sc和Sr微量元素在凝固过程中的附加作用。Sr和Sc元素的加入对共晶相的改性有显著的影响。当Sc元素添加量达到0.2 wt%时,共晶相细化,共晶相生长温度明显降低。当Sr元素的添加量达到0.02 wt%时,共晶相的生长温度降低,对共晶相的改性作用增强。添加0.02wt%Sr对共晶相的改性效果最强,共晶相的微观结构呈纤维状,长径比减小,改性比增大。通过流动性和收缩率试验来评价合金的浇注性。添加0.02wt%的Sr有效地提高了合金的流动性,而添加Sc与不添加Sc相比没有任何效果。由于细al晶粒的影响,在0.01wt%TiB-0.02wt%Sr中最大填充长度。随着共晶改性剂的加入,宏观收缩率降低,微观收缩率提高。Sr为0.02wt%时,微收缩率最高。然而,无论在本研究中添加多少,总收缩率几乎是相同的。
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Effect of Sc, Sr Elements on Eutectic Mg 2 Si Modification and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy
The effects of Sc and Sr elements on the modification of the eutectic phase and the castability were investigated in the Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurements of the cooling curve and microstructure observations were performed to analyze the additional effects of Sc and Sr minor elements during the solidification process. A prominent effect found on the modification of the eutectic phase with additions of the Sr and Sc elements. Here, a fine eutectic phase and a decrease in the growth temperature of the eutectic phase were evident with an addition of Sc element up to 0.2 wt%. The growth temperature of the eutectic phase decreased and the effect on the modification of the eutectic phase increased with the addition of Sr element up to 0.02 wt%. The addition of 0.02wt%Sr had the strongest effect on the modification of the eutectic phase, and the resulting microstructure of the eutectic phase was found to have a fibrous morphology with a decreased aspect ratio and an increased modification ratio. Fluidity and shrinkage tests were conducted to evaluate the castability of the alloy. The addition of 0.02wt%Sr effectively increased the fluidity of the alloy, while an addition of Sc did not show any effect compared to when nothing was added. The maximum filling length was recorded for 0.01wt%TiB-0.02wt%Sr owing to the effect of the fine -Al grains. The macro-shrinkage ratio decreased, while the micro-shrinkage ratio increased with the addition of various eutectic modifiers. The highest ratio of micro-shrinkage was recorded for the 0.02wt%Sr condition. However, the total shrinkage ratio was nearly identical regardless of the amounts added in this study.
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