表面活性剂对乳状液膜法分离轻稀土金属的影响

Dwi Ratna Setiani, Afifah R. Widianti, Fauzia Salsabila, A. Anggraeni, H. Bahti, U. Pratomo
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摘要

稀土金属(REM)是稀有元素,只以磷酸盐和碳酸盐的复杂化合物形式存在。快速眼动由17种元素组成,分为轻快速眼动、中快速眼动和重快速眼动。本文重点介绍轻快速眼动,它广泛应用于各个工业领域。许多REM应用程序正在增加对高纯度和批量REM的需求。然而,REM具有几乎相同的物理和化学性质,使其难以分离。因此,快速眼动蛋白的分离是目前研究的热点之一,乳化液膜法(ELM)就是其中之一。ELM正在开发一种包括三个阶段的溶剂萃取方法:外相、内相和膜相。ELM成功的关键在于乳液的稳定性,而乳液的稳定性很大程度上取决于表面活性剂的种类和浓度,因此在ELM工艺中,必须选择合适的表面活性剂的浓度和种类。因此,本文研究了span-80、span-85、T154等表面活性剂在ELM法分离轻REM中的作用。
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The Effect of Surfactants on Separation of Light Rare Earth Metals using Emulsion Liquid Membrane Method: Review
Rare earth metals (REM) are scarce elements and are only found in the form of complex compounds of phosphate and carbonate. REM consists of 17 elements classified into light REM, medium REM, and heavy REM. This article is focused on lightweight REM, which is widely applied in various industrial fields. Many REM applications are increasing the demand for high-purity and bulk REMs. However, REM has almost the same physical and chemical properties, making it difficult to separate. Therefore, the separation of REM is interesting to study with various methods, one of which is Emulsion Liquid Membrane (ELM). ELM is developing a solvent extraction method involving three phases: the external phase, the internal phase, and the membrane phase. The key to the success of ELM lies in the stability of the emulsion, which is very dependent on the type and concentration of surfactants, so in the ELM process, it is necessary to choose the right concentration and type of surfactant. Therefore, this article was made to know the effect of surfactants such as span-80, span-85, and T154 in separating light REM using the ELM method.
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