提高天然竹纤维改性环氧树脂基复合材料的机械、热、冲蚀磨损性能

Haixia Hu, Jiang Liu, Zhiwei Liu, C. Li, Chengjun Wang, Xiangyang Chen, Yuzhe Shen
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引用次数: 1

摘要

以天然竹纤维为原料,经硅烷偶联剂处理后,合成了增强环氧树脂基复合材料。利用傅里叶变换红外光谱对偶联剂对BFs化学结构的影响进行了表征。BFs/ ep基复合材料的拉伸强度、弯曲强度、冲击强度和硬度等力学性能均有显著提高,这是由于BFs具有良好的强化效果。同时,对BFs/环氧复合材料的热行为进行了实验研究,结果表明,BFs/环氧复合材料的热分解温度降低,阻燃性提高。在复合材料的冲击断裂面上还观察到竹纤维断裂和纤维劈裂现象,这反映了纤维脱粘和拉拔过程中的能量耗散。通过冲蚀磨损试验,分析了天然竹纤维改性环氧基复合材料的冲蚀磨损性能。结果表明,当天然竹纤维含量为15 wt.%时,ep基复合材料的耐冲蚀磨损性能有较大提高。
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Improving mechanical, thermal, and erosive wear performance of natural bamboo fibers modified epoxy resin matrix composites
Natural bamboo fibers (BFs), which were treated by silane coupling agents, reinforced epoxy resin (EP)–based composite were synthesized. Effects of the coupling agents on the chemical structures of the BFs were characterized by Fourier Transform Infrared Spectroscopy. The mechanical properties, such as tensile strength, flexural strength, impact strength, and hardness of the BFs/EP-based composites were improved significantly, which could be attributed to the excellent strengthening effect of the BFs. Simultaneously, experimental investigations on the thermal behaviors of the BFs/epoxy composites were also presented, indicating that the thermal decomposition temperature of the polymer materials was lowered but the flame retardancy was improved. The bamboo fiber breakage and fiber split were also observed on the impact fracture surface of the composites, which indicate energy dissipation during fiber debonding and pullout process. Moreover, the erosive wear tests have also been carried out to analyze the erosive wear properties of the natural bamboo fibers which modified the epoxy matrix composites. The results indicate that the erosive wear resistance of the EP-based composite was improved greatly when the natural bamboo fibers content was 15 wt.%.
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