{"title":"基于1,3-苯二甲酸和2-(3-吡啶基)苯并咪唑的新型双核钴(II)配合物","authors":"Quanzhen Zhang, Changkun Xia, Hongdian Lu, Rui-Xia Jiang, Xue-Ting Zhang, Xing Wang, Longzhong He","doi":"10.1080/15533174.2014.988814","DOIUrl":null,"url":null,"abstract":"A binuclear cobalt(II) complex, [Co2(H2O)4(3-PBIM)4(1,3-BDC)2]·2H2O (1,3-H2BDC = 1,3-benzenedicarboxylic acid, 3-PBIM = 2-(3-pyridyl)benzimidazole), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystallographically independent cobalt atom is coordinated by four oxygen and two nitrogen donors in an octahedron geometry ([CoN2O4]). Two cobalt coordination units ([CoN2O4]) are linked together via four carboxyl oxygen atoms of two 1,3-BDC2− ligands, forming a dimetal unit ([CoN2O4]2). The extensive hydrogen bonding interactions connects the binuclear metal units into three-dimensional framework.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A New Binuclear Cobalt(II) Complex Based on 1,3-Benzenedicarboxylic Acid and 2-(3-Pyridyl)benzimidazole\",\"authors\":\"Quanzhen Zhang, Changkun Xia, Hongdian Lu, Rui-Xia Jiang, Xue-Ting Zhang, Xing Wang, Longzhong He\",\"doi\":\"10.1080/15533174.2014.988814\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A binuclear cobalt(II) complex, [Co2(H2O)4(3-PBIM)4(1,3-BDC)2]·2H2O (1,3-H2BDC = 1,3-benzenedicarboxylic acid, 3-PBIM = 2-(3-pyridyl)benzimidazole), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystallographically independent cobalt atom is coordinated by four oxygen and two nitrogen donors in an octahedron geometry ([CoN2O4]). Two cobalt coordination units ([CoN2O4]) are linked together via four carboxyl oxygen atoms of two 1,3-BDC2− ligands, forming a dimetal unit ([CoN2O4]2). The extensive hydrogen bonding interactions connects the binuclear metal units into three-dimensional framework.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2014.988814\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988814","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A New Binuclear Cobalt(II) Complex Based on 1,3-Benzenedicarboxylic Acid and 2-(3-Pyridyl)benzimidazole
A binuclear cobalt(II) complex, [Co2(H2O)4(3-PBIM)4(1,3-BDC)2]·2H2O (1,3-H2BDC = 1,3-benzenedicarboxylic acid, 3-PBIM = 2-(3-pyridyl)benzimidazole), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystallographically independent cobalt atom is coordinated by four oxygen and two nitrogen donors in an octahedron geometry ([CoN2O4]). Two cobalt coordination units ([CoN2O4]) are linked together via four carboxyl oxygen atoms of two 1,3-BDC2− ligands, forming a dimetal unit ([CoN2O4]2). The extensive hydrogen bonding interactions connects the binuclear metal units into three-dimensional framework.
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