{"title":"路易斯酸性膦的新合成机会","authors":"N. Burford, P. Ragogna","doi":"10.1039/B208715D","DOIUrl":null,"url":null,"abstract":"Phosphines are traditional Lewis bases or ligands in transition metal complexes. In spite of their electron-rich (lone pair bearing) nature, an extensive coordination chemistry is developing for Lewis acidic phosphines, which highlights a new synthetic methodology leading to new structure and bonding.","PeriodicalId":17317,"journal":{"name":"Journal of The Chemical Society-dalton Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"82","resultStr":"{\"title\":\"New synthetic opportunities using Lewis acidic phosphines\",\"authors\":\"N. Burford, P. Ragogna\",\"doi\":\"10.1039/B208715D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Phosphines are traditional Lewis bases or ligands in transition metal complexes. In spite of their electron-rich (lone pair bearing) nature, an extensive coordination chemistry is developing for Lewis acidic phosphines, which highlights a new synthetic methodology leading to new structure and bonding.\",\"PeriodicalId\":17317,\"journal\":{\"name\":\"Journal of The Chemical Society-dalton Transactions\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-11-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"82\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society-dalton Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/B208715D\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-dalton Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B208715D","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
New synthetic opportunities using Lewis acidic phosphines
Phosphines are traditional Lewis bases or ligands in transition metal complexes. In spite of their electron-rich (lone pair bearing) nature, an extensive coordination chemistry is developing for Lewis acidic phosphines, which highlights a new synthetic methodology leading to new structure and bonding.
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