铁离子诱导氧化钒(IV)与2,2′-联吡啶的亚氨基二乙酸配合物的水化反应动力学研究

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL Progress in Reaction Kinetics and Mechanism Pub Date : 2019-05-21 DOI:10.1177/1468678319850496
Joanna Drzeżdżon, Agnieszka Piotrowska-Kirschling, L. Chmurzyński, D. Jacewicz
{"title":"铁离子诱导氧化钒(IV)与2,2′-联吡啶的亚氨基二乙酸配合物的水化反应动力学研究","authors":"Joanna Drzeżdżon, Agnieszka Piotrowska-Kirschling, L. Chmurzyński, D. Jacewicz","doi":"10.1177/1468678319850496","DOIUrl":null,"url":null,"abstract":"The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.","PeriodicalId":20859,"journal":{"name":"Progress in Reaction Kinetics and Mechanism","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2019-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Aquation reaction of iminodiacetate complex of oxidovanadium(IV) with 2,2’-bipyridine induced by Fe(III) ions: Kinetic studies\",\"authors\":\"Joanna Drzeżdżon, Agnieszka Piotrowska-Kirschling, L. Chmurzyński, D. Jacewicz\",\"doi\":\"10.1177/1468678319850496\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.\",\"PeriodicalId\":20859,\"journal\":{\"name\":\"Progress in Reaction Kinetics and Mechanism\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2019-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Reaction Kinetics and Mechanism\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/1468678319850496\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Reaction Kinetics and Mechanism","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/1468678319850496","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

研究了[Fe(H2O)6]3+离子在水溶液中促进[VO(ida)(bipy)]·2H2O (VO(ida)(bipy))配合物(ida =亚氨基二乙酸阴离子,bipy = 2,2′-联吡啶)的水化反应动力学。在293.15 ~ 313.15 K的不同温度下进行了分光光度研究。[Fe(H2O)6]3+ (Fe3+)离子浓度保持在2 × 10-4 ~ 8 × 10-4 mol L-1范围内,VO(ida)(bipy)浓度为1 × 10-3 mol L-1。利用Glint计算机程序计算了可观测到的反应速率常数。此外,还提出了由Fe(III)离子诱导VO(ida)(bipy)水化的机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Aquation reaction of iminodiacetate complex of oxidovanadium(IV) with 2,2’-bipyridine induced by Fe(III) ions: Kinetic studies
The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.10
自引率
0.00%
发文量
5
审稿时长
2.3 months
期刊介绍: The journal covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.
期刊最新文献
Understanding the rate-limiting step adsorption kinetics onto biomaterials for mechanism adsorption control Entropy controlled reaction of piperidine with isatin derivatives in 80% aqueous methanol Kinetics and mechanism of the oxidation of furfural by benzimidazolium dichromate under non aqueous medium Melting aspects in flow of second grade nanomaterial with homogeneous–heterogeneous reactions and irreversibility phenomenon: A residual error analysis Two coordination polymers: Crystal structures, prevention and nursing values on postoperative infection
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1