用糖和再生聚合物模板制备低成本碳化硅泡沫

Respuestas Pub Date : 2021-03-01 DOI:10.22463/0122820x.2107
Mayra Bayona Becerra, Elcy Córdoba Tuta, Viviana Güiza Argüello
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引用次数: 0

摘要

大孔陶瓷泡沫由于其独特的性能,包括:低密度、低导热系数、高渗透性、高温稳定性和高抗化学侵蚀性,被应用于不同的领域。高多孔碳化硅(SiC)泡沫材料由于其耐化学性、大表面积、低流动阻力、低压降以及耐高温和耐腐蚀等特点,在吸收、催化支撑和隔热应用等方面受到了极大的关注。在这项工作中,利用回收的聚合物泡沫作为牺牲模板,通过模板复制制备了高多孔碳化硅泡沫。采用含硅粉的蔗糖基树脂作为泡沫前驱体。浸渍聚合物模板,然后在1500℃惰性气氛下进行热处理。研究了前驱体中C/SiO2质量比(1.0-1.75)和氧化铝(0.5 - 2.5% wt/v)作为烧结添加剂对泡沫材料形貌和SiC收率的影响。
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Fabrication of low-cost SiC foams from sugar and recycled polymeric templates
Macroporous ceramic foams are used in different fields due to their unique properties, which include: low density, low thermal conductivity, high permeability, high temperature stability and high resistance to chemical attack. Highly porous silicon carbide (SiC) foams are materials of great interest for absorption, catalytic support, and thermal insulation applications, among others, due to their chemical resistance, large surface area, low flow resistance, low pressure drop, as well as high resistance to temperature and corrosion. In this work, highly porous, SiC foams were fabricated via template replica, using recycled polymeric foams as sacrificial templates. A sucrose-based resin containing silica powder was used as a foam precursor. Polymeric templates were impregnated, followed by thermal treatment at 1500 °C under inert atmosphere. The effect of C/SiO2 mass ratio (1.0-1.75) in the precursor and the use of alumina (0.5 - 2.5 %wt/v) as a sintering additive were evaluated in terms of the morphology of the fabricated foams, as well as SiC yield.
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