茜素染料测定铝(Iii)流动注射装置的新设计

Khadija Jabbar
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引用次数: 1

摘要

*报道了一种简便、快速的流动注射分析法(FIA)测定铝(Iii)的新方法。该方法用于测定铝(Iii)的准确、精密度。建立了茜素染料在494nm分光光度法测定铝(III)的方法。考察了影响测定铝的各种物理和化学参数,包括流速、反应线圈长度、试剂(茜素)体积、样品体积、pH和两种反应物的浓度。通过重现性来确定结果的精密度和准确度。用不同的离子对离子的干扰进行了检测。该方法允许线性范围(2 ~ 140)mg/l的测定,采样速率为每小时120个样品,FIA的检出限为0.5 mg/l。相对标准偏差为(60mg/l), n=10 (FIA为0.274%)。并对该方法在部分药品样品中的应用进行了研究。对该方法进行了色散系数的测量。
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New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye
*Corresponding Author Received 7 th July 2015, Accepted 25 th September 2015 New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye Khadija J. A and Zaid N. U * Department of Chemistry, Faculty of Education for Girls of Kufa, Iraq University Email: khdijajabar@gmail.com ABSTRACT A new simple and rapid method was reported for the accurate and precised spectrophotometric determination of Aluminum [Al (III)] using flow injection analysis (FIA). The method is based on determination of Al (III) by Alizarin dye spectrophotometrically at 494nm.The variousphysical and chemical parameters affecting on determination of Al have been investigated including flow rate, reaction coil length, and volume of reagent (Alizarin), volume of sample, pH,and concentration of both reactants.The precision and accuracy of the results were determined through reproducibility. The interferences of ions were also checked using different ions. The method allows the determination of linear range (2-140) mg/l and the sampling rate of 120 samples per hour, the detection limit (0.5 mg/l) for FIA. Relative standard deviation for (60mg/l), n=10 for the method is found (0.274% for FIA). The applications of this method were also studied for some pharmaceutical samples. Dispersion coefficient is measured for the method.
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