{"title":"茜素染料测定铝(Iii)流动注射装置的新设计","authors":"Khadija Jabbar","doi":"10.15228/2015.V05.I03.P01201509310905","DOIUrl":null,"url":null,"abstract":"*Corresponding Author Received 7 th July 2015, Accepted 25 th September 2015 New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye Khadija J. A and Zaid N. U * Department of Chemistry, Faculty of Education for Girls of Kufa, Iraq University Email: khdijajabar@gmail.com ABSTRACT A new simple and rapid method was reported for the accurate and precised spectrophotometric determination of Aluminum [Al (III)] using flow injection analysis (FIA). The method is based on determination of Al (III) by Alizarin dye spectrophotometrically at 494nm.The variousphysical and chemical parameters affecting on determination of Al have been investigated including flow rate, reaction coil length, and volume of reagent (Alizarin), volume of sample, pH,and concentration of both reactants.The precision and accuracy of the results were determined through reproducibility. The interferences of ions were also checked using different ions. The method allows the determination of linear range (2-140) mg/l and the sampling rate of 120 samples per hour, the detection limit (0.5 mg/l) for FIA. Relative standard deviation for (60mg/l), n=10 for the method is found (0.274% for FIA). The applications of this method were also studied for some pharmaceutical samples. Dispersion coefficient is measured for the method.","PeriodicalId":19815,"journal":{"name":"Pakistan Journal of Chemistry","volume":"64 1","pages":"93-100"},"PeriodicalIF":0.0000,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye\",\"authors\":\"Khadija Jabbar\",\"doi\":\"10.15228/2015.V05.I03.P01201509310905\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"*Corresponding Author Received 7 th July 2015, Accepted 25 th September 2015 New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye Khadija J. A and Zaid N. U * Department of Chemistry, Faculty of Education for Girls of Kufa, Iraq University Email: khdijajabar@gmail.com ABSTRACT A new simple and rapid method was reported for the accurate and precised spectrophotometric determination of Aluminum [Al (III)] using flow injection analysis (FIA). The method is based on determination of Al (III) by Alizarin dye spectrophotometrically at 494nm.The variousphysical and chemical parameters affecting on determination of Al have been investigated including flow rate, reaction coil length, and volume of reagent (Alizarin), volume of sample, pH,and concentration of both reactants.The precision and accuracy of the results were determined through reproducibility. The interferences of ions were also checked using different ions. The method allows the determination of linear range (2-140) mg/l and the sampling rate of 120 samples per hour, the detection limit (0.5 mg/l) for FIA. Relative standard deviation for (60mg/l), n=10 for the method is found (0.274% for FIA). The applications of this method were also studied for some pharmaceutical samples. Dispersion coefficient is measured for the method.\",\"PeriodicalId\":19815,\"journal\":{\"name\":\"Pakistan Journal of Chemistry\",\"volume\":\"64 1\",\"pages\":\"93-100\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Pakistan Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15228/2015.V05.I03.P01201509310905\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Pakistan Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15228/2015.V05.I03.P01201509310905","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye
*Corresponding Author Received 7 th July 2015, Accepted 25 th September 2015 New Design of Flow Injection Unit for Determination of Aluminum (Iii) by Alizarin Dye Khadija J. A and Zaid N. U * Department of Chemistry, Faculty of Education for Girls of Kufa, Iraq University Email: khdijajabar@gmail.com ABSTRACT A new simple and rapid method was reported for the accurate and precised spectrophotometric determination of Aluminum [Al (III)] using flow injection analysis (FIA). The method is based on determination of Al (III) by Alizarin dye spectrophotometrically at 494nm.The variousphysical and chemical parameters affecting on determination of Al have been investigated including flow rate, reaction coil length, and volume of reagent (Alizarin), volume of sample, pH,and concentration of both reactants.The precision and accuracy of the results were determined through reproducibility. The interferences of ions were also checked using different ions. The method allows the determination of linear range (2-140) mg/l and the sampling rate of 120 samples per hour, the detection limit (0.5 mg/l) for FIA. Relative standard deviation for (60mg/l), n=10 for the method is found (0.274% for FIA). The applications of this method were also studied for some pharmaceutical samples. Dispersion coefficient is measured for the method.