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Keywords:
preparation;
hexamethyl-trans-σ-trishomobenzene (2);
preparation;
olefins from vinyl halides and alkyllithiums;
beckmann fragmentation of ketoximes;
aryl- and vinyl-substituted acetylenes;
dehydrobromination of α-bromo ketones;
ketone synthesis;
extrusion of mercury from bis(propenyl)mercury;
allylation of amines;
alkenes from vinyl iodides and grignard reagents;
conjugated enynes;
arylalkynes;
unsymmetrical biaryls and diarylmethanes;
vinyl nitriles;
cyclization via π-allylpalladium complexes;
steroid side chain;
cyclization to medium-sized lactones;
chiral methyl chiral lactic acid (5);
isomerization of 1,3-diene epoxides;
alkylation of vinyl lactones;
reductive acylation of alkoxy-substituted allylic acetates;
methylenecyclopentanes;
stereospecific synthesis of alkenes;
cross-coupling of aryl halides and 1-alkenylboranes;
iboga alkaloids;
isomerization and elimination of allylic acetates;
supported reagent;
coupling of allyl bromides and allylstannanes;
decarboxylation of β-acetoxy carboxylic acids;
cleavage of endoperoxides;
alkylation of dihydropyranyl acetates;
alkylation and amination of allylic phosphates;
1,4-Dienes;
α-Allylated ketones;
alkylation of allyl nitroalkanes;
allylation of nucleophiles;
alkylation of vinyl epoxides;
vinylsilanes;
nucleophilic substitution reactions with α-acetoxy-β,γ-unsaturated nitriles;
macrocyclization;
macroheterocyclization;
β-Keto esters;
double silylation;
allylic sulfones;
2,3-Disubstituted bicyclo[2.2.1]heptanes;
desulfonylation; homoallylic alcohols;
sequential π-allylpalladium alkylation;
biaryls;
1,3-Dienes;
heterosubstituted 1,3-dienes;
1,3-Diynes;
allenynes;
coupling of vinyl triflates with organotins;
acylation of organozinc reagents;
β-Carboline synthesis;
allylation of potassium enoxyborates;
allylic amination;
macrocyclization by allylation–alkylation;
steroidal 6β-hydroxy-2,4-diene-1-ones;
trans- cis-Cinnamic acids;
RX RCHO;
coupling of vinyl triflates with alkenes;
α-Diketones;
carbonylation of 1-iodo-1,4- and -1,5-dienes;
conjugate reduction;
denitro-sulfonylation; allylic sulfones;
coupling of 1-alkenylboranes with 1-bromoalkenes or -alkynes;
cross-coupling of organoalanes with allylic acetals or ortho esters;
carbonylation; 1,4-diazepines;
decarbonylative cross coupling of acyl halides;
decarbonylation of acyl cyanides;
allylation of lithium 1-cyclopentenolates;
asymmetric allylation;
bisethynylation of vic-dichloroethylenes;
pyrrolidines; piperidines;
unsymmetrical biaryls;
primary allylic amines;
coupling of aryl triflates with organostannanes;
coupling of vinylboranes and vinyl halides;
intramolecular heck reactions;
hydroxylamination;
denitration of allylic nitro groups;
coupling of RCOCl with Bu4Pb;
intramolecular arylation;
cyclizative heck coupling;
[3 + 2]Annelation;
Pd-catalyzed intramolecular ene reactions;
allylidenation of aldehydes;
3-Aza-Cope rearrangement;
biphenyls;
coupling of alkylsilanes with aryl triflates;
(Z,E)-2-Bromo-1,3-dienes;
alkenyl sulfides;
ArOTf+AlR3 ArR;
1,2-Diene-4-ynes;
indole synthesis;
sulfones;
carbonylation of aryl and vinyl iodides;
benzylpalladation;
intramolecular heck cyclizations;
intramolecular ene reactions;
coupling of 1-alkynes and vinyl halides;
coupling of 2-bromonaphthoquinones with stannanes;
addition of (ArS)2 and (ArSe)2 to 1-alkynes;
coupling of acid chloride with (E)-Bu3SnCH CHSnBu3; 1,4-diketones;
chiral oxazolines; stille carbonylative coupling;
cyclization of triynes to benzenes;
coupling of aryl iodides and arylboronic acids;
allylic substitutions;
allylation of carbonyl compounds and imines;
coupling of organozincs with aryl halides;
coupling of organozincs with alkenyl halides;
coupling involving organoborons;
coupling of organotins with unsaturated halides;
destannylative acylation;
coupling of organosilanes with aryl halides;
cyclopropanation of norbornene;
intramolecular zinc-ene reaction;
deallylation;
stille coupling;
suzuki coupling;
other cross-couplings;
carbonylations;
allylic substitutions;
rearrangements;
cycloadditions;
hydrogenation;
allyl and propargyl group transfer;
suzuki coupling;
intramolecular coupling of phenols with haloarenes;
stille coupling;
other reactions of organostannanes;
negishi coupling;
carbonylative coupling;
arenes from enynes and diynes;
cyclization;
rearrangement;
allylic displacements;
tandem coupling and cyclization;
cyclizations and cycloadditions;
addition to alkynes;
acylations;
stille coupling;
suzuki coupling;
other coupling reactions;
rearrangements;
addition reactions;
substitution reactions;
coupling reactions;
acylation and allylation;
2-pyridylpyrroles;
coupling reactions;
decarboxylative transformations;
allylation;
cyclizations;
additions;
cycloadditions;
deprotection;
coupling reactions;
heterocycle synthesis;
cleavage of C—O bonds;
cyclization;
cycloaddition;
aminocarbonylation;
addition;
substitution;
coupling reactions;
isomerization;
tetrabutylammonium fluoride, TBAF;
tetrabutylammonium difluorotriphenylsilicate;
tetracarbonylhydridorhenium;
titanocene bis(triethyl phosphite);
trimethylsilyl trifluoromethanesulfonate
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