氯化铁(III)在聚氯乙烯薄膜中的可逆光反应

E.D. Owen, S.R. Brooks
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引用次数: 8

摘要

含FeCl3的聚氯乙烯(PVC)薄膜在300 ~ 400 nm范围内的吸收光谱具有FeCl−4的特征。在空气中辐照薄膜时,吸收强度降低,但在随后的暗反应中恢复到比辐照前更高的水平。讨论了这些体系与掺杂聚乙炔的关系。
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A reversible photoreaction of iron(III) chloride in poly(vinyl chloride) film

Poly(vinyl chloride) (PVC) films containing FeCl3 showed absorption spectra in the 300–400 nm region which were characteristic of FeCl4. On irradiation of the films in air the absorptions were reduced in intensity but were restored in a subsequent dark reaction to levels which were higher than those before irradiation. The relation between these systems and doped polyacetylene is discussed.

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