{"title":"氯化铁(III)在聚氯乙烯薄膜中的可逆光反应","authors":"E.D. Owen, S.R. Brooks","doi":"10.1016/0144-2880(85)90003-X","DOIUrl":null,"url":null,"abstract":"<div><p>Poly(vinyl chloride) (PVC) films containing FeCl<sub>3</sub> showed absorption spectra in the 300–400 nm region which were characteristic of FeCl<sup>−</sup><sub>4</sub>. On irradiation of the films in air the absorptions were reduced in intensity but were restored in a subsequent dark reaction to levels which were higher than those before irradiation. The relation between these systems and doped polyacetylene is discussed.</p></div>","PeriodicalId":101036,"journal":{"name":"Polymer Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0144-2880(85)90003-X","citationCount":"8","resultStr":"{\"title\":\"A reversible photoreaction of iron(III) chloride in poly(vinyl chloride) film\",\"authors\":\"E.D. Owen, S.R. Brooks\",\"doi\":\"10.1016/0144-2880(85)90003-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Poly(vinyl chloride) (PVC) films containing FeCl<sub>3</sub> showed absorption spectra in the 300–400 nm region which were characteristic of FeCl<sup>−</sup><sub>4</sub>. On irradiation of the films in air the absorptions were reduced in intensity but were restored in a subsequent dark reaction to levels which were higher than those before irradiation. The relation between these systems and doped polyacetylene is discussed.</p></div>\",\"PeriodicalId\":101036,\"journal\":{\"name\":\"Polymer Photochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0144-2880(85)90003-X\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Photochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/014428808590003X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/014428808590003X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A reversible photoreaction of iron(III) chloride in poly(vinyl chloride) film
Poly(vinyl chloride) (PVC) films containing FeCl3 showed absorption spectra in the 300–400 nm region which were characteristic of FeCl−4. On irradiation of the films in air the absorptions were reduced in intensity but were restored in a subsequent dark reaction to levels which were higher than those before irradiation. The relation between these systems and doped polyacetylene is discussed.