自密实混凝土非吸附性粘滞剂的研究

H. Yammamuro, T. Izumi, T. Mizunuma
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引用次数: 14

摘要

研究了自密实混凝土的一系列粘滞剂,其中一些粘滞剂对水泥颗粒无吸附倾向。结果表明,自密实混凝土的砂浆流变性受粘滞剂的吸附特性控制。桥梁结构中的纤维素衍生物等吸附黏度剂一旦吸附在砂浆中的水泥颗粒表面,就会与高效减水剂(SP)竞争占据吸附位点。这降低了砂浆的流动性。另一方面,使用非吸附粘度剂可使砂浆具有足够的流动性和粘度。此外,即使使用这种药剂,水泥颗粒上的吸附位点也保留给SP。为了了解黏性剂的工作原理,观察了黏性剂的吸附量、zeta电位和粒径分布,并考察了外加剂之间的相互作用。
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Study of Non-Adsorptive Viscosity Agents Applied to Self-Compacting Concrete
A series of viscosity agents, some of which have no tendancy to absorb onto cement particles, has been studied for self-compacting concrete. It was found that the mortar rheology of self-compacting concrete is controlled by the adsorption nature of viscosity agents. The adsorptive viscosity agents such as cellulose derivatives from bridge structures and compete with the superplasticizers (SP) to occupy at adsorption sites once the agents adsorb on the surface of the cmeent particles in the mortar.This reduces the fluidity of the mortar. A use of the non-adsorptive viscosity agents, on the other hand, accomplishes the adequate fluidity and viscosity of the mortar. In addition, the adsorption sites on the cement particles are reserved for the SP even such agents are used. In order to understand how the viscosity agents work, the adsorption amounts, the zeta potentials and the particle size distributions were observed, while the interaction between the admixtures were examined.
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