Liang Huang, Pinxian Xi, Min Xu, Tonghuan Liu, Z. Zeng
{"title":"二甲双胍·乙基N-(3-磺酰基)氨基甲酸酯的晶体结构","authors":"Liang Huang, Pinxian Xi, Min Xu, Tonghuan Liu, Z. Zeng","doi":"10.2116/ANALSCIX.24.X289","DOIUrl":null,"url":null,"abstract":"The title compound, C14H24N6O4S, was prepared by the reaction of ethyl N-(3-tossulfonyl)carbamate with metformin. It was crystallized in the triclinic system, space group P1 with a = 6.894(3)A, b = 8.323(4)A, c = 17.184(8)A, α = 84.119(7)°, β = 84.028(6)°, γ = 75.479(6)°, V = 946.4(7)A3, Z = 2, R = 0.0426. The molecules are linked by two kinds of hydrogen-bonds, N-H…N and N-H…O, generating an extended two-dimensional supramolecular network structure in the ab plane.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"12 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Crystal Structure of Metformin·ethyl N-(3-tossulfonyl)carbamate\",\"authors\":\"Liang Huang, Pinxian Xi, Min Xu, Tonghuan Liu, Z. Zeng\",\"doi\":\"10.2116/ANALSCIX.24.X289\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound, C14H24N6O4S, was prepared by the reaction of ethyl N-(3-tossulfonyl)carbamate with metformin. It was crystallized in the triclinic system, space group P1 with a = 6.894(3)A, b = 8.323(4)A, c = 17.184(8)A, α = 84.119(7)°, β = 84.028(6)°, γ = 75.479(6)°, V = 946.4(7)A3, Z = 2, R = 0.0426. The molecules are linked by two kinds of hydrogen-bonds, N-H…N and N-H…O, generating an extended two-dimensional supramolecular network structure in the ab plane.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"12 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X289\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X289","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
摘要
以甲双胍为原料，N-(3-磺酰基)氨基甲酸乙酯为原料，合成了标题化合物C14H24N6O4S。在三斜晶系P1中，空间群a = 6.894(3) a, b = 8.323(4) a, c = 17.184(8) a， α = 84.119(7)°，β = 84.028(6)°，γ = 75.479(6)°，V = 946.4(7)A3, Z = 2, R = 0.0426。分子由两种氢键N- h…N和N- h…O连接，在ab平面上形成扩展的二维超分子网络结构。
Crystal Structure of Metformin·ethyl N-(3-tossulfonyl)carbamate
The title compound, C14H24N6O4S, was prepared by the reaction of ethyl N-(3-tossulfonyl)carbamate with metformin. It was crystallized in the triclinic system, space group P1 with a = 6.894(3)A, b = 8.323(4)A, c = 17.184(8)A, α = 84.119(7)°, β = 84.028(6)°, γ = 75.479(6)°, V = 946.4(7)A3, Z = 2, R = 0.0426. The molecules are linked by two kinds of hydrogen-bonds, N-H…N and N-H…O, generating an extended two-dimensional supramolecular network structure in the ab plane.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
