凝胶JP-4池上火焰蔓延

H. Ishida, A. Iwama
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引用次数: 4

摘要

为水包油乳剂的稠化JP-4类型包括96∼99%石油浓度体积随着内部阶段和排水温度高于70°C在密闭容器中,池燃烧的火焰传播方面观察通过电影,和温度的测量,上面和凝胶的表面从火焰来了的时候已经去世了的时候,进行了用热电偶固定到位。当火焰在凝胶JP-4上蔓延时,如果初始凝胶温度低于通过开杯法测量的表观闪点(26 ~ 35°C),则可以发现火焰前面的提前液体流动。这种液体流动从已经被发光火焰覆盖的上游区域侵入到原始凝胶的表面,而不是通过从火焰柱到原始凝胶表面的辐射和传导传热形成的。从上述液体流动在凝胶表面初始水平的温度为10 ~ 20℃和原始JP-4的闪点为-23℃的角度来看,大部分低烃馏分似乎在火焰区燃烧后才流出原始凝胶表面。在点火位置附近撒上细铝粉,详细观察了液体的流动行为。结果发现,在上述液体流动中,由于温度梯度的作用,存在着强烈的对流。因此,将液体流动覆盖在原凝胶上起到了降低凝胶排液速率的作用,保护凝胶表面在靠近热火焰的地方不暴露在空气中,火焰蔓延速度比原JP-4可以抑制十分之一到二十分之一。
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Flame Spreading on Gelled JP-4 Pool
For the gelled JP-4 of an oil-in-water emulsion type which includes 96∼99% oil concentration by volume as an internal phase and has the drainage temperature higher than 70°C in confined vessel, the flame spreading aspects with a pool combustion were observed by taking movie, and the measurement of temperatures, on and above the surface of the gel from the time when the flame is coming over to the time when it has passed away, was carried out with thermocouples fixed in place.While the flame is spreading on the gelled JP-4, an advance liquid flow ahead of the flame can be found in case of the initial gel temperatures lower than the apparent flash points (26∼35°C) measured by means of open cup method. This liquid flow invades on to the surface of the virgin gel, issued from the upstream region covered already with luminous flame, and is not formed by radiative and conductive heat transfer from the flame pillar to the virgin gel surface. In view point that the temperatures of foregoing liquid flow is 10∼20°C at the initial level of gel surface and the flash point of the original JP-4 is -23°C, a large part of the low hydrocarbon fractions seem to have burned in the flame zone before streaming out on the virgin gel surface. The behavior of liquid flow was observed in detail with fine aluminum powders sowed in the vicinity of the ignition position. As the result, it is found that in the foregoing liquid flow there is a strong convection due to temperature gradient. Thus, the covering of the liquid flow on the virgin gel plays a role to reduce the drainage rate of the gel, protecting the gel surface from being exposed in air in the place close to hot flame, and the flame spreading velocity can be suppressed by one-tenth to one-twentieth, compared to that of the original JP-4.
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