Thermomechanical Constitutive Models of Shape Memory Polymers and Their Composites

Shape memory polymers (SMPs) and SMP composites (SMPCs) have been widely employed in several fields and exhibit excellent self-actuation, deformation, and self-adaption. Establishing reasonable constitutive models is vital for understanding the shape memory mechanism and expanding its applications. Moreover, the mechanical response of SMPs under different conditions can be predicted, facilitating their precise control. The internal mechanism for the shape memory behavior in most SMPs is thermal actuation. This study reviews the theories of thermally actuated SMPs, rheological and phase transition concept models, and models combining the rheology and phase transition concept. Furthermore, the constitutive models of particulate-reinforced SMPCs, carbon-fiber-reinforced SMPCs, and the buckling behavior of SMPCs are summarized. This study is expected to help solve the remaining issues rapidly and contribute to the establishment of rational constitutive models for SMPs and SMPCs.