水合硅酸钙去除径流中的重金属阳离子(铜、铅、锌):三元混合物中共离子和离子竞争的影响

M. Brogat, S. Pontvianne, L. Sigot, C. Vallières
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引用次数: 0

摘要

研究了水合硅酸钙(CSH)对铅、铜和锌的吸附行为,以考虑其在水径流中金属去除中的应用。对单金属溶液和混合溶液进行了一系列的去除动力学和等温线研究。吸附是通过钙离子交换发生的。吸附动力学采用拟二阶模型。单独研究CSH的重量容量为铅>铜>锌。与金属离子相结合的离子对去除能力有重要影响。
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Removal of Heavy Metal Cations (Copper, Lead, Zinc) from Water Runoff by Calcium Silicate Hydrate: Effect of the Co-Ion and Competition of Ions in Ternary Mixtures
The sorption behavior of calcium silicate hydrate (CSH) with respect to lead, copper and zinc was studied to consider its application to remove metal from water runoff. A series of kinetics of removal and isotherms were undertaken with single metal and mixture solutions. The sorption occurred by ion exchange with calcium. Sorption kinetics were modelled using pseudo-second order model. The weight capacities of CSH were lead > copper >> zinc when studied separately. The co-ion associated to the metal ion is of importance on the removal capacities.
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