溶胶-凝胶法制备ZnO-Аg纳米颗粒

S. Janković, Dragana Milisavić, Tanja Okolić, Dijana Jelić
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引用次数: 1

摘要

氧化锌是一种应用非常广泛的半导体材料。这种纳米材料的广泛应用与宽谱能带隙、高键能、高导热性以及其无毒、抗菌、生物相容性和生物降解性等特性有关。采用溶胶-凝胶法制备了银掺杂ZnO纳米粒子(ZnO:Ag NP)并进行了表征。采用傅里叶变换红外光谱(FTIR)、紫外/可见分光光度法、x射线衍射(XRD)、扫描电镜(SEM)和能量色散x射线光谱(EDX)等技术对银掺杂ZnO纳米颗粒进行了表征。通过FTIR光谱复制验证了所提合成方法的有效性。XRD测定了合成材料的纯度、结晶度和纤锌矿结构。采用SEM和EDX表征方法考察了掺杂对表面形貌的影响。结果表明,银掺杂ZnO纳米粒子后,ZnO纳米粒子的导电性更好。SEM显微图显示ZnO:Ag NP以纳米棒的形式存在,平均粒径为6 nm。
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SYNTHESIS OF ZnO-Аg NANOPARTICLES BY SOL-GEL METHOD
Zinc oxide is a highly applicable semiconductor material. Wide applica-tion of this nanomaterial is connected to wide spectrum of energy band gap, high bond en-ergy, great thermal conductivity, but also with its non-toxicity, antibacterial activity, bio-compatibility and biodegradability characteristics. The aim of this paper is synthesis and characterization of silver doped ZnO nanoparticles (ZnO:Ag NP) using sol-gel method. Ob-tained samples of silver doped ZnO nanoparticles were characterized by following tech-niques: Fourier-transform infrared spectroscopy (FTIR), UV/VIS spectrophotometry, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spec-troscopy (EDX). Efficiency of provided synthesis method was examined by FTIR spectros-copy. XRD determined the purity and crystallinity, and wurtzite structure of synthesized material. Surface morphology and the effect of doping were examined using SEM and EDX characterization methods. Results showed better conductivity after doping ZnO nanoparti-cles with silver. SEM micrographs showed ZnO:Ag NP in the form of nanorods with a par-ticle average size of 6 nm.
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