可持续生物丁醇和未来的绿色汽油

Y. Dahman
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引用次数: 5

摘要

版权所有:©2012 Dahman Y.这是一篇在知识共享署名许可下发布的开放获取文章,该许可允许在任何媒体上不受限制地使用、分发和复制,前提是要注明原作者和来源。2001年至2025年期间,世界能源消费预计将增长54%,为满足未来需求,发展碳中和能源和可持续能源已成为人们关注的重点[1]。化石燃料的减少、环境的恶化和传统燃料价格的波动重新引起了人们对开发可再生燃料的兴趣。对温室气体排放、能源短缺和对能源独立的渴望的担忧正在加快生物燃料研究和商业化的步伐和强度。生物燃料是目前石油基燃料的一种有吸引力的替代品,因为它们可以用作运输燃料,而对当前技术的改变很小;它们在提高可持续性和减少温室气体排放方面也具有巨大潜力。液体(即乙醇、丁醇、生物柴油)或气体(即甲烷或氢气)生物燃料通常由有机材料生产,如淀粉、油籽和动物脂肪或纤维素和农业生物质。在南非、俄罗斯等一些国家,ABE发酵工艺由于原料和劳动力成本较低,仍然具有竞争力,但到了20世纪60年代,由于原料成本的提高和石化工业的进步,在其他国家已经失去了竞争力[2]。自20世纪90年代末以来,全球生物燃料研究稳步上升,出现了新的改性微生物、预处理、工艺配置和技术,从而提高了转化效率,降低了生产成本。在第一代生物燃料中,从粮食作物中提取的植物糖和淀粉通过酵母发酵制成生物燃料。第二代生物燃料的出现扩大了原料基础,通过在各种工艺配置中加入化学或酶水解,将非食品纤维素生物质包括在内[3]。第三代生物燃料利用藻类等产酶微生物来水解植物聚合物并发酵产生的糖。加拿大政府在2007年联邦预算中承诺投入20亿美元支持生物燃料生产的发展。长期以来,联邦和省对可再生燃料免征消费税,这鼓励了可再生燃料与汽油竞争。在美国,根据能源部(DOE)题为“美国生物质技术路线图”的报告,生物基运输燃料预计将从2001年的0.5%增加到2010年的4%,到2020年增加到10%,到2030年进一步增加到20-30%,或每年约600亿加仑汽油当量。除此之外,每年工业能源消耗还需要100 - 120亿磅的丁醇[4]。
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Sustainable Biobutanol and Working towards the Green Gasoline of the Future
Copyright: © 2012 Dahman Y. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. With world energy consumption predicted to increase 54% between 2001 and 2025, primary attention has been directed towards the development of carbon neutral energy and sustainable sources to meet the future needs [1]. Reductions of fossil fuels, environmental deterioration, and fluctuating prices of traditional fuels have revived an interest in the development of renewable fuels. Concerns regarding green house gas emission, energy scarcity and the desire for energy independence are increasing the pace and intensity of biofuel research and commercialization. Biofuels are an attractive substitute to current petroleum based fuels because they can be utilized as transportation fuels with diminutive change to current technologies; they also have significant potential to improve sustainability and reduce greenhouse gas emissions. Liquid (i.e., ethanol, butanol, biodiesel) or gaseous (i.e., methane or hydrogen) biofuels are generally produced from organic materials such as starch, oilseeds and animal fats or cellulose and agricultural biomass. While in some countries such as South Africa and Russia, ABE fermentation process remained competitive due to the low raw material and labor costs, it had lost competitiveness in other countries by 1960s, owing to the increase of feedstock costs and advancement of the petrochemical industry [2]. Since the late 1990s global biofuel research has steadily been on the rise, with new modified micro-organisms, pretreatments, process configurations and technologies, thereby improving conversion efficiencies and decreasing production cost. In first-generation biofuel, plant sugars and starch from food crops were fermented to biofuel by yeast. The advent of second-generation biofuels broadened the feedstock base to include non-food cellulosic biomass by incorporating chemical or enzymatic hydrolysis in various process configurations [3]. Third-generation biofuels employed enzyme-producing micro-organisms such as algae, to hydrolyze plant polymers and ferment the resulting sugars. The Canadian government supports the development of biofuel production through a $2 billion commitment in the 2007 Federal Budget. A longstanding federal and provincial excise tax exemption on renewable fuels has encouraged the renewable fuels to be competitive with gasoline. In the United States, according to a report from the Department of Energy (DOE) titled “Roadmap for Biomass Technology in the United States”, bio-based transportation fuels are projected to increase from 0.5% of U.S consumption in 2001 to 4% in 2010, 10% in 2020, and further to 20-30% in 2030, or about 60 billion gallons of gasoline equivalent per year. This is in addition to 10–12 billion pounds of butanol annually required for industrial energy consumption [4].
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