稻壳灰中二氧化硅纳米颗粒的提取及其复合材料制备研究

Bimal Kumar Raut, Khim Prasad Panthi
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引用次数: 3

摘要

纳米技术是不同科学研究领域中最新兴的领域。纳米颗粒的合成方法多种多样。湿法化学合成法适用于稻壳灰(RHA)中二氧化硅纳米颗粒的提取。稻壳是碾米业产生的一种废料,在国内及周边地区大量生产。稻壳通常作为废弃物留在田间,其二氧化硅含量为60%,可作为提取二氧化硅的经济可行原料[1-2]。最初,稻壳被焚烧以获得稻壳的灰。然后,采用一种简单的自下而上的方法,即溶胶-凝胶法,提取纳米范围内的细粉二氧化硅。提取后用XRD分析了二氧化硅的内部排列和平均粒径,用FTIR分析了二氧化硅的分子组成和结构。将所得的二氧化硅用于制备陶瓷基纳米复合材料(特别是硅砂水泥块),并利用Instron试验机对其进行抗压强度测试,其力学性能与相同配比、相同模具尺寸制备的陶瓷基纳米复合材料(砂水泥块)相比,抗压强度有所提高。陶瓷基纳米复合材料获得比陶瓷复合材料更高的机械强度是由于二氧化硅纳米颗粒的掺入。
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Extraction of Silica Nanoparticles from Rice Husk Ash (RHA) and Study of Its Application in Making Composites
Nanotechnology is the most emerging field in the area of different scientific research. Various methods of synthesis of nanoparticles are available. The wet chemical synthesis method is applicable in the extraction of silica nanoparticles from Rice Husk Ash (RHA). Rice husk is a form of waste product from the rice milling industries which is produced in an abundance amount in and around the country. Rice husk which is generally left on the field as a waste contains 60% silica content and can be economically viable raw materials for the extraction of silica [1-2]. Initially, Rice husk was burnt to obtain its ash. Then, a simple bottom-up approach, the sol-gel method was applied, and fine powder silica in the nanoscopic range was extracted. After extraction of it, internal arrangement and average particle size were recognized by XRD while molecular components and structure present in silica were identified by FTIR. The obtained silica was then used in making of ceramics matrix nanocomposites (particularly silica-sand cement block), and its mechanical properties were identified by compressive strength test using Instron testing machine which was found to be increased in comparing with the compressive strength of ceramics composite (Sand cement block) prepared in the same ratio and same size of mold as that of ceramics matrix nanocomposites. The ceramics matrix nanocomposites acquiring higher mechanical strength than Ceramics composite occurred due to the incorporation of Silica nanoparticles.
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