低温共沉淀法制备COxNi1-xFe2O4 (x=0,0.25,0.5,0.75,1.0)纳米颗粒

M. Yakob, R. A. Putra
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引用次数: 1

摘要

采用共沉淀法在低温120℃下通过改变浓度(x=0;0.25;0.5;0.75;1.0)。晶体结构和晶粒尺寸随钴浓度的增加而增大。理论晶格与实验晶格存在差异。增加CoxNi1-xFe2O4纳米颗粒中钴的浓度会影响四面体和八面体上正阴离子之间的键长。由于变形,晶体形成不完全,出现晶体缺陷。用微应变值来表示晶体中应变的大小。
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NANOPARTICLE FABRICATION OF COxNi1-xFe2O4 (x=0,0.25,0.5,0.75,1.0) USING CO-PRECIPITATION METHODE AT LOW TEMPERATURE

Nanoparticle CoxNi1-xFe2O4 has been successfully synthesized using co-precipitation method at low temperature 120oC by variation of concentration value (x=0; 0.25; 0.5; 0.75; 1.0). Crystal structure and size of crystallite increase with increasing cobalt concentration. There is a difference of lattice between theoretical and experimental. Increase the cobalt concentration in CoxNi1-xFe2O4 nanoparticle affected to the bond length between cation-anion on tetrahedral site and octahedral site. Because of the distortion, the crystallite where imperfectly formed and crystal defect occurred. It is indicated by the microstrain value that describes the magnitude of the strain in crystal.

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