J. Dilworth, John R. Miller, N. Wheatley, M. J. Baker, J. Sunley
{"title":"甲醇羰基化反应的新型催化剂","authors":"J. Dilworth, John R. Miller, N. Wheatley, M. J. Baker, J. Sunley","doi":"10.1039/C39950001579","DOIUrl":null,"url":null,"abstract":"Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"20 1","pages":"1579-1581"},"PeriodicalIF":0.0000,"publicationDate":"1995-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"66","resultStr":"{\"title\":\"Novel catalysts for the carbonylation of methanol\",\"authors\":\"J. Dilworth, John R. Miller, N. Wheatley, M. J. Baker, J. Sunley\",\"doi\":\"10.1039/C39950001579\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"20 1\",\"pages\":\"1579-1581\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-12-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"66\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001579\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001579","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported.
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