非橡胶成分对银胶菊和橡胶树橡胶特性的影响

Shirin Monadjemi, C. McMahan, K. Cornish
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引用次数: 16

摘要

为了满足对天然橡胶(NR)日益增长的需求,并解决价格波动和劳动力成本稳步上升的问题,替代橡胶生产物种正在进行商业开发。目前,天然橡胶主要来源于热带橡胶树巴西橡胶树(Hevea brasiliensis)。其中之一,银胶菊(Parthenium argentatum),已经出现在市场上作为高品质橡胶的商业来源。非橡胶组分对NR制品的物理性能起着重要的作用。两种NR材料的内在组成不同,这些差异可能是它们之间性能差异的主要原因。我们比较了非橡胶成分,如蛋白质、脂类、树脂和橡胶颗粒膜的效果。首先,采用薄膜浇铸法获得厚度均匀的橡胶薄膜。其次,通过动态力学分析确定了不同橡胶的玻璃化转变温度,并对未复合材料的拉伸性能进行了测试。胶乳形式(MRGNR)的银胶菊天然橡胶(GNR)具有比GNR或无胶天然橡胶(FNR)更高的固有强度。丙酮萃取法定量测定橡胶样品中的树脂和游离脂质。
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Effect of Non-Rubber Constituents on Guayule and Hevea Rubber Intrinsic Properties
To meet the increasing demand for natural rubber (NR), currently sourced from the tropical rubber tree Hevea brasiliensis , and address price volatility and steadily increasing labor costs, alternate rubber-producing species are in commercial development. One of these, guayule ( Parthenium argentatum ), has emerged on the market as a commercial source of high quality rubber. Non-rubber constituents play an important role in the physical properties of NR products. The intrinsic composition of the two NR materials differs and these differences may be a principal cause of the performance differences between them. We have compared the effect of non-rubber constituents, such as protein, lipids, resin and rubber particle membranes. Firstly, a film casting method was developed to obtain rubber films with a uniform thickness. Secondly, the glass transition temperature of different rubbers was determined by dynamic mechanical analysis, and tensile properties were tested for uncompounded materials. Guayule natural rubber (GNR), from which most of the membranes were removed while in latex form (MRGNR) was found to have higher intrinsic strength than GNR or gel-free NR (FNR). An acetone extraction was performed to quantify the resin and free lipids in the rubber samples.
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