{"title":"金属-磷键的配体K-Edge XAS研究:应用、限制和机遇","authors":"Courtney M. Donahue, Scott R. Daly","doi":"10.1080/02603594.2018.1465938","DOIUrl":null,"url":null,"abstract":"Phosphorus K-edge X-ray absorption spectroscopy (XAS) is a highly effective experimental method for investigating metal-phosphorus bonding and electronic structure. Here, we provide a comprehensive review of P K-edge XAS studies of transition metal complexes and show how they were used to investigate a wide range of chemical phenomena, including covalent metal-ligand bonding, redox non-innocence in ligands, molecular magnetism, and luminescence. Limitations of the technique are discussed along with opportunities for future work.","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"11 1","pages":"54 - 78"},"PeriodicalIF":3.8000,"publicationDate":"2018-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Ligand K-Edge XAS Studies of Metal-Phosphorus Bonds: Applications, Limitations, and Opportunities\",\"authors\":\"Courtney M. Donahue, Scott R. Daly\",\"doi\":\"10.1080/02603594.2018.1465938\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Phosphorus K-edge X-ray absorption spectroscopy (XAS) is a highly effective experimental method for investigating metal-phosphorus bonding and electronic structure. Here, we provide a comprehensive review of P K-edge XAS studies of transition metal complexes and show how they were used to investigate a wide range of chemical phenomena, including covalent metal-ligand bonding, redox non-innocence in ligands, molecular magnetism, and luminescence. Limitations of the technique are discussed along with opportunities for future work.\",\"PeriodicalId\":10481,\"journal\":{\"name\":\"Comments on Inorganic Chemistry\",\"volume\":\"11 1\",\"pages\":\"54 - 78\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2018-03-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comments on Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/02603594.2018.1465938\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comments on Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/02603594.2018.1465938","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Ligand K-Edge XAS Studies of Metal-Phosphorus Bonds: Applications, Limitations, and Opportunities
Phosphorus K-edge X-ray absorption spectroscopy (XAS) is a highly effective experimental method for investigating metal-phosphorus bonding and electronic structure. Here, we provide a comprehensive review of P K-edge XAS studies of transition metal complexes and show how they were used to investigate a wide range of chemical phenomena, including covalent metal-ligand bonding, redox non-innocence in ligands, molecular magnetism, and luminescence. Limitations of the technique are discussed along with opportunities for future work.
期刊介绍：
Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts.
Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.
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