{"title":"改进半透明碳电极循环测定1,2 -二羟基苯","authors":"S. Deepa, D. Kathirvel","doi":"10.13074/jent.2022.03.221449","DOIUrl":null,"url":null,"abstract":"An avoltammetric 1, 2-dihydroxy benzeneassay regarding the utilization of a glassy/translucent carbon electrode (GCE) customized with a grapheme oxide and polycyanurotramine (GO/PM) composition is described. Field fluorescence, SEM, FTIR elemental composition, Raman spectroscope, were used to analyze the enhanced GCE. When comparing conductors adjusted with GO or PM alone, electrochemistry demonstrates a well-defined sensitivity to 1,2-dihydroxy benzene, with an oxidationpeak present that is much higher. The composite's simultaneous synergistically action of GO and PM resulting in a decreased oxidation potential. In the detection limit of 0.03 to 138 M 1, 2-dihydroxy benzene, differentiating pulse voltammetry (DPV) displays a constant value. The sensibility is 0.537 A M1cm2 and the detection limit is 8 nM. Though in the context of theoretically contaminants notably dopamine, hydroquinone, resorcinol and the detector is discriminating for 1, 2-dihydroxybenzene. The modified GCE for detecting 1, 2-dihydroxy benzene in samples collected is extremely repeatable, durable, and accurate, and it has great applicability.","PeriodicalId":36296,"journal":{"name":"Journal of Water and Environmental Nanotechnology","volume":"4 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"MODIFYING TRANSLUCENT CARBON ELECTRODE FOR RECURRENT DETERMINATION OF 1, 2-DIHYDROXY BENZENE\",\"authors\":\"S. Deepa, D. Kathirvel\",\"doi\":\"10.13074/jent.2022.03.221449\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An avoltammetric 1, 2-dihydroxy benzeneassay regarding the utilization of a glassy/translucent carbon electrode (GCE) customized with a grapheme oxide and polycyanurotramine (GO/PM) composition is described. Field fluorescence, SEM, FTIR elemental composition, Raman spectroscope, were used to analyze the enhanced GCE. When comparing conductors adjusted with GO or PM alone, electrochemistry demonstrates a well-defined sensitivity to 1,2-dihydroxy benzene, with an oxidationpeak present that is much higher. The composite's simultaneous synergistically action of GO and PM resulting in a decreased oxidation potential. In the detection limit of 0.03 to 138 M 1, 2-dihydroxy benzene, differentiating pulse voltammetry (DPV) displays a constant value. The sensibility is 0.537 A M1cm2 and the detection limit is 8 nM. Though in the context of theoretically contaminants notably dopamine, hydroquinone, resorcinol and the detector is discriminating for 1, 2-dihydroxybenzene. The modified GCE for detecting 1, 2-dihydroxy benzene in samples collected is extremely repeatable, durable, and accurate, and it has great applicability.\",\"PeriodicalId\":36296,\"journal\":{\"name\":\"Journal of Water and Environmental Nanotechnology\",\"volume\":\"4 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-03-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Water and Environmental Nanotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.13074/jent.2022.03.221449\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Water and Environmental Nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.13074/jent.2022.03.221449","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0
摘要
本文描述了一种利用氧化石墨烯和多氰尿胺(GO/PM)组合物定制的玻璃/半透明碳电极(GCE)的1,2 -二羟基苯的伏安法测定。利用场荧光、SEM、FTIR元素组成、拉曼光谱等对增强GCE进行分析。当比较单独使用氧化石墨烯或PM调整的导体时,电化学表明对1,2-二羟基苯具有明确的敏感性,并且存在更高的氧化峰。复合材料的同时协同作用的氧化石墨烯和PM导致氧化电位降低。在1,2-二羟基苯的检出限为0.03 ~ 138 M时,差分脉冲伏安法(DPV)呈恒定值。灵敏度为0.537 A M1cm2,检出限为8 nM。虽然在理论上污染物的背景下,特别是多巴胺,对苯二酚,间苯二酚和检测器是区分1,2 -二羟基苯。改进的GCE用于样品中1,2 -二羟基苯的检测具有重复性好、耐用性好、准确度高的特点,具有很强的适用性。
MODIFYING TRANSLUCENT CARBON ELECTRODE FOR RECURRENT DETERMINATION OF 1, 2-DIHYDROXY BENZENE
An avoltammetric 1, 2-dihydroxy benzeneassay regarding the utilization of a glassy/translucent carbon electrode (GCE) customized with a grapheme oxide and polycyanurotramine (GO/PM) composition is described. Field fluorescence, SEM, FTIR elemental composition, Raman spectroscope, were used to analyze the enhanced GCE. When comparing conductors adjusted with GO or PM alone, electrochemistry demonstrates a well-defined sensitivity to 1,2-dihydroxy benzene, with an oxidationpeak present that is much higher. The composite's simultaneous synergistically action of GO and PM resulting in a decreased oxidation potential. In the detection limit of 0.03 to 138 M 1, 2-dihydroxy benzene, differentiating pulse voltammetry (DPV) displays a constant value. The sensibility is 0.537 A M1cm2 and the detection limit is 8 nM. Though in the context of theoretically contaminants notably dopamine, hydroquinone, resorcinol and the detector is discriminating for 1, 2-dihydroxybenzene. The modified GCE for detecting 1, 2-dihydroxy benzene in samples collected is extremely repeatable, durable, and accurate, and it has great applicability.