改进半透明碳电极循环测定1,2 -二羟基苯

S. Deepa, D. Kathirvel
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引用次数: 0

摘要

本文描述了一种利用氧化石墨烯和多氰尿胺(GO/PM)组合物定制的玻璃/半透明碳电极(GCE)的1,2 -二羟基苯的伏安法测定。利用场荧光、SEM、FTIR元素组成、拉曼光谱等对增强GCE进行分析。当比较单独使用氧化石墨烯或PM调整的导体时,电化学表明对1,2-二羟基苯具有明确的敏感性,并且存在更高的氧化峰。复合材料的同时协同作用的氧化石墨烯和PM导致氧化电位降低。在1,2-二羟基苯的检出限为0.03 ~ 138 M时,差分脉冲伏安法(DPV)呈恒定值。灵敏度为0.537 A M1cm2,检出限为8 nM。虽然在理论上污染物的背景下,特别是多巴胺,对苯二酚,间苯二酚和检测器是区分1,2 -二羟基苯。改进的GCE用于样品中1,2 -二羟基苯的检测具有重复性好、耐用性好、准确度高的特点,具有很强的适用性。
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MODIFYING TRANSLUCENT CARBON ELECTRODE FOR RECURRENT DETERMINATION OF 1, 2-DIHYDROXY BENZENE
An avoltammetric 1, 2-dihydroxy benzeneassay regarding the utilization of a glassy/translucent carbon electrode (GCE) customized with a grapheme oxide and polycyanurotramine (GO/PM) composition is described. Field fluorescence, SEM, FTIR elemental composition, Raman spectroscope, were used to analyze the enhanced GCE. When comparing conductors adjusted with GO or PM alone, electrochemistry demonstrates a well-defined sensitivity to 1,2-dihydroxy benzene, with an oxidationpeak present that is much higher. The composite's simultaneous synergistically action of GO and PM resulting in a decreased oxidation potential. In the detection limit of 0.03 to 138 M 1, 2-dihydroxy benzene, differentiating pulse voltammetry (DPV) displays a constant value. The sensibility is 0.537 A M1cm2 and the detection limit is 8 nM. Though in the context of theoretically contaminants notably dopamine, hydroquinone, resorcinol and the detector is discriminating for 1, 2-dihydroxybenzene. The modified GCE for detecting 1, 2-dihydroxy benzene in samples collected is extremely repeatable, durable, and accurate, and it has great applicability.
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来源期刊
Journal of Water and Environmental Nanotechnology
Journal of Water and Environmental Nanotechnology Materials Science-Materials Science (miscellaneous)
CiteScore
2.40
自引率
0.00%
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0
审稿时长
8 weeks
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