{"title":"阳极钼的电化学氧化成卤素的非水溶液","authors":"Jacob J. Habeeb, Colin Oldham, Dennis G. Tuck","doi":"10.1016/0022-1902(81)80554-4","DOIUrl":null,"url":null,"abstract":"<div><p>A molybdenum anode can be oxidised electrochemically into acetonitrile/X<sub>2</sub> media (X = Cl, Br, I), with current efficiencies which are lower than for the analogous chromium system. The subsequent work-up of solutions prepared by this method yields products containing molybdenum in either + II or + V oxidation states. A tentative reaction scheme is presented. Tungsten could not be oxidised electrochemically under the conditions used.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 9","pages":"Pages 2087-2088"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80554-4","citationCount":"4","resultStr":"{\"title\":\"The electrochemical oxidation of anodic molybdenum into non-aqueous solutions of halogen\",\"authors\":\"Jacob J. Habeeb, Colin Oldham, Dennis G. Tuck\",\"doi\":\"10.1016/0022-1902(81)80554-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A molybdenum anode can be oxidised electrochemically into acetonitrile/X<sub>2</sub> media (X = Cl, Br, I), with current efficiencies which are lower than for the analogous chromium system. The subsequent work-up of solutions prepared by this method yields products containing molybdenum in either + II or + V oxidation states. A tentative reaction scheme is presented. Tungsten could not be oxidised electrochemically under the conditions used.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 9\",\"pages\":\"Pages 2087-2088\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80554-4\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281805544\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281805544","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The electrochemical oxidation of anodic molybdenum into non-aqueous solutions of halogen
A molybdenum anode can be oxidised electrochemically into acetonitrile/X2 media (X = Cl, Br, I), with current efficiencies which are lower than for the analogous chromium system. The subsequent work-up of solutions prepared by this method yields products containing molybdenum in either + II or + V oxidation states. A tentative reaction scheme is presented. Tungsten could not be oxidised electrochemically under the conditions used.
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