S. H. Hosseini, Amir Abbas Kazemi, Seyed Arash Hosseini
{"title":"电场法制备聚咔唑纳米纤维及其电导率研究","authors":"S. H. Hosseini, Amir Abbas Kazemi, Seyed Arash Hosseini","doi":"10.3390/nanomanufacturing3010007","DOIUrl":null,"url":null,"abstract":"In conventional chemical and electrochemical oxidation methods, it is very difficult to control the active centers, and the average prepared polymers are short and wide. The use of an electric field creates the most stable intermediate form of active centers, as well as permitting a longer half-life. Therefore, this increases the physical resistance and electrical conductivity of the polymer. In this paper, polycarbazole nanofibers were prepared using an electric field, reporting on its influences on the polymerization of carbazole. Therefore, its electrical conductivity and some physical properties were investigated. We observed the nanofibers’ shape, increasing electrical conductivity, thermal resistance and a higher molecular weight with the synthesized polycarbazole under an electric field compared to the polymer synthesized in the same conditions in the absence of an electric field. First, we chemically synthesized polycarbazole at different times. Additionally, to find the optimizing conditions, we changed certain parameters, such as the ratio of the obtained molar of initiator to monomer, the oxidant, initiator and solvent, separately, and compared the obtained results. Then, we repeated this reaction in the best conditions and under different electric fields in constant time, allowing us to characterize the shape, mass and conductivity. Next, the polymerization was carried out at the best electric field in different times. Finally, the best time and amount of electric field for polymerization were determined. The electrical conductivity of polycarbazoles was studied with the four-probe method. The conductivity of the films oxidized using FeCl3 (dry) and protonated with p-toluenesulfonic acid (PTSA) at 3 h was higher than 8.9 × 10−4 S/cm under a 12 KV/m electric field. Additionally, the results showed an enhanced thermal resistance to ageing.","PeriodicalId":52345,"journal":{"name":"Nanomanufacturing and Metrology","volume":"76 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of Polycarbazole Nanofibers Using an Electric Field and the Investigation of Its Electrical Conductivity\",\"authors\":\"S. H. Hosseini, Amir Abbas Kazemi, Seyed Arash Hosseini\",\"doi\":\"10.3390/nanomanufacturing3010007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In conventional chemical and electrochemical oxidation methods, it is very difficult to control the active centers, and the average prepared polymers are short and wide. The use of an electric field creates the most stable intermediate form of active centers, as well as permitting a longer half-life. Therefore, this increases the physical resistance and electrical conductivity of the polymer. In this paper, polycarbazole nanofibers were prepared using an electric field, reporting on its influences on the polymerization of carbazole. Therefore, its electrical conductivity and some physical properties were investigated. We observed the nanofibers’ shape, increasing electrical conductivity, thermal resistance and a higher molecular weight with the synthesized polycarbazole under an electric field compared to the polymer synthesized in the same conditions in the absence of an electric field. First, we chemically synthesized polycarbazole at different times. Additionally, to find the optimizing conditions, we changed certain parameters, such as the ratio of the obtained molar of initiator to monomer, the oxidant, initiator and solvent, separately, and compared the obtained results. Then, we repeated this reaction in the best conditions and under different electric fields in constant time, allowing us to characterize the shape, mass and conductivity. Next, the polymerization was carried out at the best electric field in different times. Finally, the best time and amount of electric field for polymerization were determined. The electrical conductivity of polycarbazoles was studied with the four-probe method. The conductivity of the films oxidized using FeCl3 (dry) and protonated with p-toluenesulfonic acid (PTSA) at 3 h was higher than 8.9 × 10−4 S/cm under a 12 KV/m electric field. Additionally, the results showed an enhanced thermal resistance to ageing.\",\"PeriodicalId\":52345,\"journal\":{\"name\":\"Nanomanufacturing and Metrology\",\"volume\":\"76 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanomanufacturing and Metrology\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://doi.org/10.3390/nanomanufacturing3010007\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanomanufacturing and Metrology","FirstCategoryId":"1089","ListUrlMain":"https://doi.org/10.3390/nanomanufacturing3010007","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}
Preparation of Polycarbazole Nanofibers Using an Electric Field and the Investigation of Its Electrical Conductivity
In conventional chemical and electrochemical oxidation methods, it is very difficult to control the active centers, and the average prepared polymers are short and wide. The use of an electric field creates the most stable intermediate form of active centers, as well as permitting a longer half-life. Therefore, this increases the physical resistance and electrical conductivity of the polymer. In this paper, polycarbazole nanofibers were prepared using an electric field, reporting on its influences on the polymerization of carbazole. Therefore, its electrical conductivity and some physical properties were investigated. We observed the nanofibers’ shape, increasing electrical conductivity, thermal resistance and a higher molecular weight with the synthesized polycarbazole under an electric field compared to the polymer synthesized in the same conditions in the absence of an electric field. First, we chemically synthesized polycarbazole at different times. Additionally, to find the optimizing conditions, we changed certain parameters, such as the ratio of the obtained molar of initiator to monomer, the oxidant, initiator and solvent, separately, and compared the obtained results. Then, we repeated this reaction in the best conditions and under different electric fields in constant time, allowing us to characterize the shape, mass and conductivity. Next, the polymerization was carried out at the best electric field in different times. Finally, the best time and amount of electric field for polymerization were determined. The electrical conductivity of polycarbazoles was studied with the four-probe method. The conductivity of the films oxidized using FeCl3 (dry) and protonated with p-toluenesulfonic acid (PTSA) at 3 h was higher than 8.9 × 10−4 S/cm under a 12 KV/m electric field. Additionally, the results showed an enhanced thermal resistance to ageing.
期刊介绍:
Nanomanufacturing and Metrology is a peer-reviewed, international and interdisciplinary research journal and is the first journal over the world that provides a principal forum for nano-manufacturing and nano-metrology.Nanomanufacturing and Metrology publishes in the forms including original articles, cutting-edge communications, timely review papers, technical reports, and case studies. Special issues devoted to developments in important topics in nano-manufacturing and metrology will be published periodically.Nanomanufacturing and Metrology publishes articles that focus on, but are not limited to, the following areas:• Nano-manufacturing and metrology• Atomic manufacturing and metrology• Micro-manufacturing and metrology• Physics, chemistry, and materials in micro-manufacturing, nano-manufacturing, and atomic manufacturing• Tools and processes for micro-manufacturing, nano-manufacturing and atomic manufacturing