金属烯醇类化合物非电化学分析方法研究进展

J. Zabicky
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引用次数: 0

摘要

这一章是2009年出版的一章的更新,涵盖了截至2014年秋季的文献。由于本书各章篇幅所限,对分析方法的回顾分为两部分,本章的附文涉及电化学分析方法,本章涉及所有其他分析方法,特别是分光光度法和光学方法。在选择分析方法时,遵循与前一章相同的指导方针,即:一节处理特定金属烯醇化物的检测和测定,一节处理金属阳离子分析物在结束分析之前转化为烯醇化配体的配合物,一节介绍某些金属烯醇化物作为分析辅助和工具的使用。关键词:色谱法;显色传感器;提取;fluorogenic传感器;metal-enol情结;金属烯化分析;装置
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Recent Advances in Nonelectrochemical Analytical Methods Involving Metal Enolates
The chapter is an update of one published in 2009, covering the literature up to the autumn of 2014. Due to space limitations assigned to chapters in this book, the review of analytical methods was divided into two parts, the companion of this chapter dealing with electrochemical methods of analysis and the present one dealing with all the rest, especially spectrophotometric and optical methods. The same guidelines as in the older chapter were followed for the selection of analytical methods, namely: A section dealing with detection and determination of specific metal enolates, a section dealing with conversion of metal cation analytes into complexes with enolic ligands before end analysis and a section presenting the use of certain metal enolates as analytical aids and tools. Keywords: chromatography; chromogenic sensors; extraction; fluorogenic sensors; metal-enol complexes; metal enolate analysis; optodes
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