原位合成(TiB + TiC)/Ti复合材料的微观结构和压缩性能

W. Lu, Di Zhang, Xiaonong Zhang, R. Wu, T. Sakata, H. Mori
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引用次数: 7

摘要

利用钛与b4c、石墨的自扩散高温合成反应,采用非耗材电弧熔炼技术制备了TiB和TiC增强钛基复合材料。采用x射线衍射(XRD)对复合材料中的相进行了表征。利用扫描电镜(SEM)、透射电镜(TEM)和高分辨率透射电镜(HREM)对复合材料的微观结构进行了观察。结果表明:复合材料中存在TiB、TiC和钛基合金三种相,增强物在基体中均匀分布;TiB生长成短纤维状,TiC生长成树枝状、等轴状。增强材料与钛基合金的界面非常干净。没有任何界面反应。TiC颗粒周围存在高密度位错。由于加入了增强剂,机械性能得到了改善。铝的加入不仅可以通过固溶强化对钛基合金进行强化,还可以通过细化增强剂和基体合金来改善复合材料的力学性能。
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Microstructure and Compressive Properties of In Situ Synthesized (TiB + TiC)/Ti Composites
TiB and TiC reinforced titanium matrix composites have been produced by non-consumable arc-melting technology utilizing the self-propagation high-temperature synthesis reactions between titanium and B 4 C, graphite. X-ray diffraction (XRD) was used to identify the phases in the composites. Microstructures of composites have been observed by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HREM). The results show that there are three phases in the composite: TiB, TiC and titanium matrix alloy, Reinforcements are distributed uniformly in the matrix. TiB grows in short-fiber shape and TiC grows in dendritic, equiaxed shapes. The interfaces between reinforcements and titanium matrix alloy are very clean. There is no any interfacial reaction. There are high-density dislocations around TiC particle. Mechanical properties have been improved due to the incorporation of reinforcements. The addition of aluminum not only strengthens the titanium matrix alloy by solid solution strengthening, but also improves the mechanical properties of composites by refining the reinforcements and matrix alloy.
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