碱聚铝酸盐作为催化剂和镍催化剂对烃类蒸汽重整的催化活性研究

S. Komatsu, G. Yamaguchi
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引用次数: 1

摘要

碳氢化合物的蒸汽重整通常用于生产城镇煤气和合成气。在高压下连续蒸汽重整似乎是最经济的,但它的缺点是碳的沉积,使在最经济的汽油比下操作困难。但ICI公司开发的碱化镍催化剂解决了这一难题。S. P. S. Andrew1)曾报道,这种催化剂由难熔载体和流动碱组成,可加速蒸汽与沉积的碳之间的反应。进一步发现,钾硅石(K.Al.SiO4)是碱化镍催化剂最理想的碱源。
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Studies on the Catalytic Activity of Alkali Polyaluminate as a Catalyst and Support of Nickel Catalyst for Steam Reforming of Hydrocarbons
Steam reforming of hydrocarbons is generally used for production of town gas and synthetic gas. Continuous steam reforming under high pressure seems most economical, but its disadvantage is the deposition of carbon that made operation under the most economical steam/oil ratio difficult. But this difficulty has been removed by the development of alkalized nickel catalyst by ICI Co., Ltd. S. P. S. Andrew1) has reported that this catalyst consists of a refractory support and mobil alkali which accelerates the reaction between steam and the deposited carbon. It is further found that kalsilite (K.Al.SiO4) is the most desirable alkali source for the alkalized nickel catalyst.
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