{"title":"甲烷的动态酸度","authors":"A. Streitwieser, David R. Taylor","doi":"10.1039/C29700001248","DOIUrl":null,"url":null,"abstract":"The rate of deuterium exchange of methane with caesium cyclohexylamide in cyclohexylamine at 50° is 3·1 × 10–2 that of cyclopropane, on a perhydrogen-atom basis.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"100 1","pages":"1248-1248"},"PeriodicalIF":0.0000,"publicationDate":"2003-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"11","resultStr":"{\"title\":\"Kinetic acidity of methane\",\"authors\":\"A. Streitwieser, David R. Taylor\",\"doi\":\"10.1039/C29700001248\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The rate of deuterium exchange of methane with caesium cyclohexylamide in cyclohexylamine at 50° is 3·1 × 10–2 that of cyclopropane, on a perhydrogen-atom basis.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"100 1\",\"pages\":\"1248-1248\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-07-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29700001248\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29700001248","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The rate of deuterium exchange of methane with caesium cyclohexylamide in cyclohexylamine at 50° is 3·1 × 10–2 that of cyclopropane, on a perhydrogen-atom basis.
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