{"title":"一些新的(吡唑和三唑)香豆素衍生物的表面和简单合成","authors":"H. A. Latif, M. Barsy, E. Elrady","doi":"10.9790/5736-1005012326","DOIUrl":null,"url":null,"abstract":"2-oxo-2H-coumarin-3-carbohydrazide (2) which prepared from the reaction of ethyl-2-oxo-2Hcoumarin-3-carboxylate (1) with hydrazine hydrate in ethanol containing a catalytic amount of piperidine mixture consider a good and available starting intermediate for synthesis of series of functionalized coumarins. So, compound (2) was utilized as a key for the synthesis of some new (pyrazole, triazole)-2Hcoumarin-2-one derivatives by the reaction with some selected reagents.","PeriodicalId":14488,"journal":{"name":"IOSR Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2017-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facial and Simple Synthesis of Some New (Pyrazole and Triazole) Coumarin Derivatives\",\"authors\":\"H. A. Latif, M. Barsy, E. Elrady\",\"doi\":\"10.9790/5736-1005012326\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"2-oxo-2H-coumarin-3-carbohydrazide (2) which prepared from the reaction of ethyl-2-oxo-2Hcoumarin-3-carboxylate (1) with hydrazine hydrate in ethanol containing a catalytic amount of piperidine mixture consider a good and available starting intermediate for synthesis of series of functionalized coumarins. So, compound (2) was utilized as a key for the synthesis of some new (pyrazole, triazole)-2Hcoumarin-2-one derivatives by the reaction with some selected reagents.\",\"PeriodicalId\":14488,\"journal\":{\"name\":\"IOSR Journal of Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IOSR Journal of Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.9790/5736-1005012326\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IOSR Journal of Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9790/5736-1005012326","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
由乙基-2-氧-2-香豆素-3-羧酸酯(1)与水合肼在含有催化量哌替啶混合物的乙醇中反应制备的2-氧-2- h -香豆素-3-碳肼(2)是合成一系列功能化香豆素的良好的起始中间体。因此,以化合物(2)为关键,通过与选定的试剂反应,合成了一些新的(吡唑、三唑)-2 - h香豆素-2- 1衍生物。
Facial and Simple Synthesis of Some New (Pyrazole and Triazole) Coumarin Derivatives
2-oxo-2H-coumarin-3-carbohydrazide (2) which prepared from the reaction of ethyl-2-oxo-2Hcoumarin-3-carboxylate (1) with hydrazine hydrate in ethanol containing a catalytic amount of piperidine mixture consider a good and available starting intermediate for synthesis of series of functionalized coumarins. So, compound (2) was utilized as a key for the synthesis of some new (pyrazole, triazole)-2Hcoumarin-2-one derivatives by the reaction with some selected reagents.