提高化学用棉纤维素反应性的研究

R. Sayfutdinov, U. Mukhitdinov, N. Eshpulatov
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引用次数: 5

摘要

在化学处理过程中,棉浆的反应活性明显低于从其他含纤维素植物中获得的纤维素。提高棉纤维素的反应性可以提高棉纤维素制品的质量,也可以提高劳动生产率。本研究的目的是通过提高棉纤维素的化学加工反应活性,提高产物质量,提高反应速率,研究国产棉纤维素替代国外进口木浆的可能性。在这项工作中,我们使用了测定棉花纤维素样品的组成和结构的方法。研究了所得样品经电荷处理后的乙酰化反应性。根据计算机控制的XRD-6100仪器(日本岛津)记录的衍射图,通过晶体面积的减少来评估反应性的增加。提出了一种用高压电荷处理棉花纤维素以提高其反应性的方法。为了减少棉花纤维素的结晶面积,它被电荷激活,这导致棉花纤维素的反应性增加。找到了最佳的电压限制、脉冲数和电容器所需的电容,在这些限制下,棉纤维素的反应活性达到最大值。
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RESEARCH OF INCREASING THE REACTIVITY COTTON CELLULOSE INTENDED FOR CHEMISTRY
The reactivity of cotton pulp during chemical processing is significantly lower compared to celluloses obtained from other cellulose-containing plants. Increasing the reactivity of cotton cellulose improves the quality of the products based on it, and also increases labor productivity. The aim of this work is to study the possibility of replacing wood pulp imported from foreign countries with domestic cotton cellulose by increasing the reactivity of cotton cellulose for chemical processing, improving the quality of the resulting product and increasing the reaction rate. In this work, we used methods for determining the composition and structure of cotton cellulose samples. The reactivity of the obtained samples to acetylation after treatment with electric charges was studied. An increase in reactivity was evaluated by a decrease in crystalline areas based on diffract grams that were recorded on a computer-controlled XRD-6100 apparatus (Shimadzu, Japan). A method is proposed for increasing the reactivity of cotton cellulose by treating it with high voltage electric charges. To reduce the crystalline areas of cotton cellulose, it was activated by an electric charge, which led to an increase in the reactivity of cotton cellulose. The optimal voltage limits are found, the number of pulses and the required capacitance of the capacitor, at which the maximum values of the reactive activity of cotton cellulose are achieved.
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