{"title":"由柔性聚羧酸酯和双(吡啶基)配体构建的新型三维柱状层状Zn(II)配位聚合物","authors":"Hui-min Liu","doi":"10.1080/15533174.2015.1137048","DOIUrl":null,"url":null,"abstract":"A new Zn(II) coordination polymer, namely [Zn3(TTHA)(bpp)(H2O)3]n·4n(H2O) (1 H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, bpp = 1,3-di(4-pyridyl)propane), has been synthesized by the hydrothermal self-assembly of Zn(NO3)2·6H2O, H6TTHA and bpp. Single-crystal x-ray diffraction analysis reveals that compound 1 features a 3D framework, which can be described as the 2D layers constructed by the Zn(II) ions and TTHA6– ligands pillared by the bpp ligands. Furthermore, the thermal stability and luminescent property of compound 1 were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A New 3D Pillar-Layered Zn(II) Coordination Polymer Constructed From the Mixed Flexible Polycarboxylate and Bis(pyridyl)-Based Ligands\",\"authors\":\"Hui-min Liu\",\"doi\":\"10.1080/15533174.2015.1137048\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new Zn(II) coordination polymer, namely [Zn3(TTHA)(bpp)(H2O)3]n·4n(H2O) (1 H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, bpp = 1,3-di(4-pyridyl)propane), has been synthesized by the hydrothermal self-assembly of Zn(NO3)2·6H2O, H6TTHA and bpp. Single-crystal x-ray diffraction analysis reveals that compound 1 features a 3D framework, which can be described as the 2D layers constructed by the Zn(II) ions and TTHA6– ligands pillared by the bpp ligands. Furthermore, the thermal stability and luminescent property of compound 1 were investigated.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137048\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137048","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A New 3D Pillar-Layered Zn(II) Coordination Polymer Constructed From the Mixed Flexible Polycarboxylate and Bis(pyridyl)-Based Ligands
A new Zn(II) coordination polymer, namely [Zn3(TTHA)(bpp)(H2O)3]n·4n(H2O) (1 H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, bpp = 1,3-di(4-pyridyl)propane), has been synthesized by the hydrothermal self-assembly of Zn(NO3)2·6H2O, H6TTHA and bpp. Single-crystal x-ray diffraction analysis reveals that compound 1 features a 3D framework, which can be described as the 2D layers constructed by the Zn(II) ions and TTHA6– ligands pillared by the bpp ligands. Furthermore, the thermal stability and luminescent property of compound 1 were investigated.
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