纳米结构在氧化物-镍阴极发射特性形成中的作用

V. Kapustin, I. Li, N. E. Kozhevnikova
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引用次数: 0

摘要

利用电子能谱和精密x射线结构分析研究了含纳米镍和纳米碳酸钡的三元钡钙锶碳酸盐氧化物镍组合物的电子结构和晶体结构。研究发现,纳米镍对这些成分在热处理过程中形成的氧化钡晶体的电子结构参数有显著影响。结果表明,x射线衍射分析可作为三元碳酸盐的质量控制方法的基础,使其有效地用于氧化物-镍阴极的组成。
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The role of nanostructures in the formation of the emission properties of oxide-nickel cathodes
The electronic and crystal structures of oxide-nickel compositions based on ternary barium-calcium-strontium carbonates containing nickel nanoparticles and nanocrystals of barium carbonate have been studied by electron spectroscopy and precision X-ray structural analysis. It was found that nickel nanoparticles have a significant effect on the parameters of the electronic structure of barium oxide crystallites formed in these compositions during their heat treatment. It is shown that X-ray diffraction analysis can be used as the basis for the method of quality control of ternary carbonates for their effective use in the composition of oxide-nickel cathodes.
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