氟塑料扩散系数和活化能的测定

IF 0.6 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Annales De Chimie-science Des Materiaux Pub Date : 2020-08-20 DOI:10.18280/acsm.440309
Lakel Abdelghani
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引用次数: 0

摘要

本研究的目的是使用氟塑料扫描量热计研究四种样品,这些样品含有不同浓度的不同分散的热延伸石墨(GTD)。我们注意到加热速度起着非常重要的作用。将加热速度从5°C/min提高到10°C/min,然后提高到15°C/min,无论浓度和/或分散程度如何,都可以改变无限小化合物的热行为。所有曲线都包含量热曲线中的异常。后者的形状、激发能量和强度取决于其集中和分散。量热计曲线的异常温度随样品的不同而变化。我们已经证明,含有最小GTD浓度、高分散性和以最高加热速度升温的纳米材料在高温下会变质。它更能抵抗热冲击。这项工作的一个有趣的结果是,在聚合物中引入一定数量的GTD,可以改善无限小化合物的热性能,并且可以在很宽的温度范围内使用。
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Determination of the Diffusion Coefficient and the Activation Energy of Fluoroplastics
Received: 16 January 2020 Accepted: 20 March 2020 The aim of this research is to study four samples using the fluoroplastic scanning calorimeter which contain different concentrations of thermally extended graphite (GTD) in different dispersions. We noticed that the heating speed plays a very important role. Increasing the heating speed from 5 to 10 then 15 °C/min, changes the thermal behavior of an infinitesimally small compound regardless of the concentration and/or dispersion. All curves each contain an anomaly in the calorimetric curves. The shape of the latter, its energizing energy, and its intensity depend on the concentration and dispersion. The temperature of anomalies in the calorimeter curve changes from one sample to another. We have shown that nanomaterials that contain the smallest GTD concentration with high dispersion and heat up at the highest heating speed deteriorate at high temperatures. It is more resistant to thermal shocks. One of the interesting results of this work the introduction of an amount of GTD in to the polymer improves the thermal properties of the infinitesimal compound, and its use becomes possible in a wide range of temperature.
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来源期刊
Annales De Chimie-science Des Materiaux
Annales De Chimie-science Des Materiaux 工程技术-材料科学:综合
CiteScore
1.70
自引率
25.00%
发文量
33
审稿时长
>12 weeks
期刊介绍: The ACSM is concerning the cutting-edge innovations in solid material science. The journal covers a broad spectrum of scientific fields, ranging all the way from metallurgy, semiconductors, solid mineral compounds, organic macromolecular compounds to composite materials. The editorial board encourages the submission of original papers that deal with all aspects of material science, including but not limited to synthesis and processing, property characterization, reactivity and reaction kinetics, evolution in service, and recycling. The papers should provide new insights into solid materials and make a significant original contribution to knowledge.
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